A Perturbed Rotational State Treatment of Collisions between Polar Molecules

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概要

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• The low-energy umolecule-naolecule collisions are studied eta the basis of tlteperturbed rotational state (PRS) functions, which are defined for the systeuta of twopolar molecules interacting with each other by the<lipole-dipole ixvteraction. Bymaking use of the PRS functions as a basis set, a se?aaic]assical iutapact-paranaetercalculation is carr'ied out to deternaine rotational tr;tnsitiota probabilities in HF-IF collisions. It is deutaonstrated that a near-resonautt rotation-to-rotation emaergytra?tsfer has a large probability aucd the relevant cross section is deterrrtinedpredomiuaantly by the long-range dipole-dipole force, and that the suna of tlvequantunt numbers 777 (projections of the rotatioutal angular zmomenta) of twopolar ?avo]ecu]es is fil<ely to be conserved.

• 社団法人日本物理学会の論文
• 1980-10-15

著者

• TSUCHIYA Soji

  Department of Pure and Applied Science, College of General Education, university of Tokyo

• Tsuchiya Soji

  Department Of Pure And Applied Science College Of General Education University Of Tokyo

• HASHI Makoto

  Department of Pure and Applied Sciences,College of General Education,University of Tokyo

• TAKAYANAGI Kazuo

  Institute of Space and Aeronautical Science,University of Tokyo

• Hashi Makoto

  Department Of Pure And Applied Sciences College Of General Education University Of Tokyo

• Takayanagi Kazuo

  Institute Of Space And Aeronautical Science University Of Tokyo

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