Microwave Spectrum of Vinylidene Chloride

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概要

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• The microwave spectrum of vinylindene chloride has been observed and analyzed. The molecular parameters have been determined to be d_<CCI> = 1.727A and ∠Cl C C = 123°10' on the assumption of d_<CC> = 1.32A, d_<OH> = 1.07A and ∠H C C = 120°. The quadrupole coupling constant along the bond direction has been found to be -78.7Mc together with the asymmetry parameter η = 0.12, for Cl^<35>. The five percent double bond character of C Cl bond estimated from the quadrupole data is consistent with the value of six percent estimated from the bond length.

• 社団法人日本物理学会の論文
• 1957-01-05

著者

• Nishikawa Tetsuji

  Department Of Physics Faculty Of Science University Of Tokyo:(present)institute For Nuclear Study Un

• Nishikawa Tetsuji

  Department Of Physics Faculty Of Sciencc University Of Tokyo

• SEKINO Shozo

  Department of Physics, Faculty of Science, University of Tokyo

• Sekino Shozo

  Department Of Physics Faculty Of Science University Of Tokyo:(present)technical Laboratory Of Yahata

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