Fine Structure of J=1←0 Transition due to Internal Rotation in Methyl Alcohol
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The fine structure of J=1←0 lines in various isotopic species of methyl alcohol has been explained by a combination method of Itoh's theory for a rigid asymmetric hinded rotor and Kivelson's theory for a nonrigid symmetric hindered rotor. All lines have been fitted within errors of 2 Mc by this method. From the analysis the height of potential barrier to internal rotation for CH_30D has been determined to be 371±5cm^<-1>. The molecular structure of methyl alcohol has also been calculated and discussed.
- 社団法人日本物理学会の論文
- 1956-07-05
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