Liquid-Solid Transitions in Systems of Soft Repulsive Forces : Softness of Potentials and a Maximum in Melting Curves
スポンサーリンク
概要
- 論文の詳細を見る
Liquid-Solid transitions are investigated from both the liquid and the solid sides and it is shown that a maximum in melting curves occurs owing to a certain kind of softness of repulsive forces. This confirms the mechanism of this phenomenon proposed previously by the use of lattice models. For the liquid free energy, the Mansoori and Canfield variational method is used, which yields an effective volume- and temperature-dependent hard-sphere packing fraction. The solid free energy is calculated by means of the Lennard-Jones and Devonshire cell model, the Lindemann fraction also being evaluated. The freezing criterion which states that the packing fraction is constant along the freezing curve and the melting curve are both shown to be approximately valid near the maximum melting point, including the region of descending melting curves.
- 理論物理学刊行会の論文
- 1974-09-25
著者
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Kamakura Shiro
Department Of Cardiovascular Surgery National Cardiovascular Center
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Shirao Kuniaki
国立がんセンター中央病院 腫瘍内科
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Shirao Kuniaki
Department Of Medical Oncology National Cancer Center Hospital
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Kamakura Shiro
Department Of Cardiology National Cardiovascular Center
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Kamakura Shiro
Department Of Physics College Of General Education Kyushu Industrial University
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YOSHIDA Takeshi
Department of Gastroenterology, Hokkaido University Graduate School of Medicine
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Yoshida Takeshi
Department Of Biochemistry Hokkaido University School Of Dentistry
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YOSHIDA Tatsuo
Faculty of Science, Ibaraki University
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YOSHIDA Tatsuo
Faculty of Sciences, Ibaraki University
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Yoshida Takeshi
Department of Applied Physics, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
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KAMAKURA Shiro
Department of Medical Oncology, National Cancer Center Hospital
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Yoshida Takeshi
Department of Applied Chemistry, Faculty of Engineering, Kanagawa University
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