Molecular Structure and Absorption Spectra of Carotenoids

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概要

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• An assemblage of π-electrons in the chain of carotenoid molecules is discussed, according to Tomonaga's method, on the basis of an assumption that the electrons are kept in a pipe whose length is equal to the chain length of conjugated double bonds. The spin degrees of freedom of electrons are taken into account though Tomonaga disregarded them. The one-dimensional potential of two-electron forces is assumed to be given by an average of the Coulomb repulsive potential over a section of the pipe. The calculated values of absorption maxima are in good agreement with experiment for carotenoids. The adequacy of the method is discussed.

• 理論物理学刊行会の論文

著者

• Araki Gentaro

  Faculty Of Engineering Kyoto Univeristy

• Murai Tomokazu

  Faculty Of Engineering Kyoto University

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• Molecular Structure and Absorption Spectra of Carotenoids
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• Free-Electron Model of Benzene
• Free-Electron Ring Model of Polyacenes

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