Free-Electron Model of Benzene

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概要

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• Lower excited electronic levels of benzene are calculated by assuming π electrons to move freely in a ring whose perimeter is equal to that of the benzene molecule. The interaction between π electrons is assumed to be the long range part separated from the Coulomb interaction by the zero cut-off at 0.46l of the ring coordinate where l is the distance between adjacent carbons in the benzene molecule. The configuration interaction with the adjacent levels is taken into account. All interaction integrals can easily be evaluated without any neglect. The calculated result agrees fairly well with experiment in spite of simpleness of the model.

• 理論物理学刊行会の論文

著者

• Araki Gentaro

  Faculty Of Engineering Kyoto Univeristy

関連論文

• Electronic States of C_2-Molecule, III : Numerical Values and Reduction Formulas of Integrals
• Electronic States of C_2-Molecule, II : Effect of 2s-Shells
• Absorption Spectra of Unsymmetrical Cyanines
• Recoil Effect on Electron-Proton Forces and Inapplicability of Energy Law
• Molecular Structure and Absorption Spectra of Carotenoids
• Partial Description of Quantum-Mechanical System
• Free-Electron Model of Benzene
• Free-Electron Ring Model of Polyacenes

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