Absorption Spectra of Unsymmetrical Cyanines

スポンサーリンク

概要

• 論文の詳細を見る

• The absorption maximum of an unsymmetrical cyanine with two different end nuclei is generally of the shorter wave length than a mean value of absorption maxima of two symmetrical cyanines with the respective nuclei. Two different simple models are found for describing this fact. The first is a modification of the free-electron model which is based on an assumption that the influence of end nuclei on the π electrons in the conjugated chain can be represented by the Poschl-Teller potential. The second is the Herzfeld-Sklar model which is based on the consideration of the interaction between various chemical states of cyanine ions. Both the models can fairly reproduce the observed fact.

• 理論物理学刊行会の論文

著者

• Araki Gentaro

  Faculty Of Engineering Kyoto Univeristy

• Huzinaga Sigeru

  Faculty Of Engineering Kyoto University

関連論文

• Electronic States of C_2-Molecule, III : Numerical Values and Reduction Formulas of Integrals
• Electronic States of C_2-Molecule, II : Effect of 2s-Shells
• A Device to Avoid Difficult Integrals in Calculations on Molecular Structure
• Absorption Spectra of Unsymmetrical Cyanines
• Recoil Effect on Electron-Proton Forces and Inapplicability of Energy Law
• Molecular Structure and Absorption Spectra of Carotenoids
• Partial Description of Quantum-Mechanical System
• Free-Electron Model of Benzene
• Free-Electron Ring Model of Polyacenes

スポンサーリンク