Theory of Phase Transitions in Solid Methanes. VII : The Intermolecular Potential and the Crystalline Field

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概要

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• The interaction between methane molecules in the solid state is discussed under the assumption of the pairwise interatomic interaction. A formal expression for the intermolecular interaction is derived in a form reflecting both molecular orientations and molecular symmetry. The isotropic part of this expression is compared with the potentials obtained from the second virial coefficients. The anisotropic parts dependent on the orientations of both molecules are worked out and compared with the James-Keenan model. Furthermore, the crystalline fields are obtained which a methane molecule feels in rare gas matrices as well as in solid methane.

• 理論物理学刊行会の論文
• 1971-05-25

著者

• Yasuda Hideo

  Department Of Chemistry Faculty Of Science Kyoto University

• YASUDA Hideo

  Department of Chemistry, Faculty of Science, Kyoto University

関連論文

• Theory of Phase Transitions in Solid Methanes. IV : Upper Transition Temperatures in Solid CH__3D and CHD_3 and Solid Solution of CH_4 and CD_4
• Theory of Phase Transitions in Solid Methanes. VII : The Intermolecular Potential and the Crystalline Field
• On the Two-Center Expansion of an Arbitrary Function

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