Syntheses of Bioactive Bisabolane-Type Cryptomeria japonica Sesquiterpenes

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概要

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• The first diastereoselective synthesis of (1S,6R)-1-hydroxy-2,7(14),10-bisabolatrien-4-one, an antifeedant against Acusta despesta and Locusta migratoria, was produced from Cryptomeria japonica (commonly known as Japanese cedar), starting from (R)-(−)-carvone via (R)-(−)-cryptomerione. The enantiomer was transformed into (1S,3R,6R)-1-hydroxy-7(14),10-bisaboladien-4-one, a novel antifeedant against L. migratoria from the same tree, by 1,4-selective reduction of the enone moiety.

• 社団法人 日本農芸化学会の論文
• 2009-03-23

著者

• Kuwahara Yasumasa

  Department Of Bioscience And Biotechnology Faculty Of Bioenvironmental Science Kyoto Gakuen Universi

• Shimizu Nobuhiro

  Department Of Bioscience And Biotechnology Faculty Of Bioenvironmental Science Kyoto Gakuen Universi

• Shimizu Nobuhiro

  Department Of Biology Faculty Of Science Kyushu University

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• Syntheses of Bioactive Bisabolane-Type Cryptomeria japonica Sesquiterpenes

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