Preparation of Single-Enantiomer Biofunctional Molecules with (S)-2-Methoxy-2-(1-naphthyl) propanoic Acid
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概要
- 論文の詳細を見る
(RS)-β-Ionol and (RS)-2-methyl-4-octanol were resolved by using (S)-2-methoxy-2-(1-naphthyl)propanoic acid [(S)-MαNP acid]. The specific stereochemistry of each MαNP ester was elucidated by 2D NMR analyses, and shielding by the 1-naphthyl group was observed in both the 1H- and 13C-NMR spectra. Solvolysis of the individual (S)-MαNP esters gave four single-enantiomer alcohols. The normal-phase HPLC elution order of each MαNP ester is also discussed.
- 社団法人 日本農芸化学会の論文
- 2008-09-23
著者
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市川 明生
農業生物資源研究所・昆虫神経生理
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Ichikawa A
Tokyo Inst. Technol. Tokyo Jpn
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Ichikawa Akio
National Institute Of Agrobiological Sciences
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Ono Hiroshi
Analytical Science Division National Food Research Institute
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Ichikawa Akio
Division Of Insect Sciences National Institute Of Agrobiological Sciences
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