Self-Assembled Complexes of Non-cross-linked Amphiphilic Polymeric Ligands with Inorganic Species : Highly Active and Reusable Solid-Phase Polymeric Catalysts
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概要
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I present herein the development of highly active and reusable polymeric catalysts produced by self-assembly process of non-cross-linked amphiphilic polymeric ligands with inorganic species. Thus, PWAA 1 prepared from H_3PW_<12>O_<40> and poly[(N-isopropylacrylamide)-co-(acrylamide with ammonium salt)] is suitable for oxidation of alcohols, amines, and sulfides in aqueous hydrogen peroxide. PdAS 2 produced by self-organization of (NH_4)_2PdCl_4 and poly[(N-isopropylacrylamide)_<10>-co-diphenylphosphinostyrene] is an excellent recyclable catalyst for Suzuki-Miyaura reaction in water, water-organic solvent, and organic solvent. It is commercially available from Tokyo Kasei Kogyo (TCI). PdAS-V 3 assembled from (NH_4)_2PdCl_4 and poly[(N-isopropylacrylamide)_5-co-diphenylphosphinostyrene] provides recycling system of itself for Mizorogi-Heck reaction. TiSS 4 made from Ti(O-i-Pr)_4 and poly(styryl-linked binaphtholate-co-styrene) promotes an enantioselective carbonyl-ene reaction as a recyclable catalyst.
- 2005-07-01
著者
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Yamada Yoichi
Instituate for Molecular Science of Medicine
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Yamada Yoichi
Institute For Molecular Science
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