A Facile One-Pot Benzylation of Sodium Enolates Using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide
スポンサーリンク
概要
- 論文の詳細を見る
A facile one-pot C-benzylation of various sodium enolates derived from methyl malonate, β-ketoesters, a β-cyanoester, a β-cyanosulfone, ketones and a carboxylic ester is reported. Reaction of alkoxydiphenylsulfonium salts formed by treating various benzyl alcohols with diphenyl sulfide bis (trifluoromethanesulfonate) (derived from trifluoromethanesulfonic anhydride and diphenyl sulfoxide) proceeded smoothly, and the corresponding C-benzylated products were afforded in good to high yields.
- 公益社団法人日本薬学会の論文
- 2005-05-01
著者
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MINOWA Tomofumi
Center for Basic Research, The Kitasato Institute
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MUKAIYAMA Teruaki
Center for Basic Research, The Kitasato Institute
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FUJISAWA Hidehiko
Center for Basic Research, The Kitasato Institute
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Minowa Tomofumi
Center For Basic Research The Kitasato Institute
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Minowa Tomofumi
Kitasato Institute For Life Sciences Kitasato University
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Mukaiyama Teruaki
The Kitasato Institute Center For Basic Research
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Mukaiyama T
Center For Basic Research The Kitasato Institute
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Takuwa Tomofumi
Center For Basic Research The Kitasato Institute
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Mukaiyama Teruaki
Center For Basic Res. The Kitasato Inst.
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Fujisawa Hidehiko
Center For Basic Research The Kitasato Institute
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