Lithium Acetate-catalyzed Mannich-type Reaction between Trimethylsilyl Enolates and Aldimines in a Water-containing DMF
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概要
- 論文の詳細を見る
- 2004-07-05
著者
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Mukaiyama Teruaki
The Kitasato Institute Center For Basic Research
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Takahashi Eiki
Kitasato Institute For Life Sciences Kitasato University
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Fujisawa Hidehiko
Kitasato Institute For Life Sciences Kitasato University
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Mukaiyama Teruaki
Kitasato Institute For Life Sciences Kitasato University
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Mukaiyama Teruaki
Kitasato Inst. For Life Sciences Kitasato Univ.
関連論文
- Cyanation of Alcohols with Diethyl Cyanophosphonate and 2,6-Dimethyl-1,4-benzoquinone by a New Type of Oxidation-Reduction Condensation
- Preparation of Nitriles from Primary Alcohols by a New Type of Oxidation-reduction Condensation Using 2, 6-Dimethyl-1, 4-benzoquinone and Diethyl Cyanophosphonate
- A Convenient Method for the Synthesis of Dialkyl Ethers by Alkylation of Alcohols Using Phosphinimidates in the Presence of a Catalytic Amount of Trimethylsilyl Triflate
- Lewis Base-Catalyzed [2,3]-Wittig Rearrangement of Silyl Enolates Generated from α-Allyloxy Carbonyl Compounds
- The Product-catalyzed [2,3]-Wittig Rearrangement of Silyl Enolates Generated from α-Allyloxy Ketones
- Ammonium Carboxylate-catalyzed [2,3]-Witting Rearrangement of Silyl Enolates Generated from α-Allyloxy Esters
- Ammonium Phenoxides-catalyzed syn-Selective Aldol Reaction Between an Aldehyde and an Trimethylsilyl Enolate
- Lewis Base-catalyzed [2, 3]-Wittig Rearrangement of Silyl Enolates Generated from α-Allyloxy Ketones
- N-Arylation of Pyridin-2(1H)-ones with Pentavalent Organobismuth Reagents under Copper-Free Conditions
- Enantioselective Synthesis of 3,4-Dihydropyran-2-ones by Chiral Quaternary Ammonium Phenoxide-catalyzed Tandem Michael Addition and Lactonization
- An Efficient Synthesis of 3, 4-Dihydropyran-2-one Derivatives by Lewis Base-catalyzed Tandem Michael Addition and Lactonization
- Lithium Alkoxide-promoted Michael Reaction between Silyl Enolates and α, β-Unsaturated Carbonyl Compounds
- Stereospecific C-S Bond Formation from Chiral Tertiary Alcohols by Quinone-Mediated Oxidation-Reduction Condensation Using Alkyl Diphenylphosphinites and Its Application to the Synthesis of a Chiral Tertiary Thiol
- New methods for carbon–nitrogen, carbon–sulfur, and carbon–carbon bond formations by quinone-mediated oxidation–reduction condensation using alkyl diphenylphosphinites
- Convenient Methods for the Preparation of Unsymmetrical Double Aldols
- Trimethylsilyl Triflate Mediated New Carbon-Carbon Bond Forming Reactions between Benzyl Diphenylphosphinates and Organosilicon Compounds
- An Efficient Method for the Ether Forming Reaction between Alkyl Diphenylphosphinate and Alkoxytrimethylsilane by the Promotion of Trimethylsilyl Triflate
- Catalytic and Chemoselective Glycosylation between "Armed" and "Disarmed" Glycosyl p-Trifluoromethylbenzylthio-p-trifluoromethylphenyl Formimidates
- Lewis Base-catalyzed Alkynylation of Carbonyl Compounds with Trimethylsilylacetylenes
- A Convenient Method for Carbon Extension of Acetals and Aldehydes by the Use of Ketenedithioacetal and Nucleophiles
- A New Method for the Synthesis of Carboxylic Esters and Lactones with Di-2-thienyl Carbonate (2-DTC) by the Promotion of DMAP and Iodine
- Lewis Base-catalyzed Cyanomethylation of Aldimines with Trimethylsilylacetonitrile
- Highly Stereoselective Samarium(II) Iodide-Mediated Aldol Reactions of Acylaziridines with Aldehydes
- Highly trans-Selective Synthesis of β-Lactams by Tandem Phenoxide Anion-catalyzed Mannich-type Addition and Cyclization
- Efficient Method for the Lactonization of ω-Hydroxycarboxylic Acids with Di-2-thienyl Carbonate by the Promotion of Catalytic Amounts of DMAP and Hf(OTf)_4
- Enantioselective Synthesis of C11-C17 Segment of Mycinolide IV Using Samarium(II) Iodide-mediated Aldol Reaction
- A Facile One-Pot Benzylation of Sodium Enolates Using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide
- Stereoselective Synthesis of 19-Hydroxytaxoid by Utilizing Samarium(II) Iodide-Mediated Double Aldol Cyclization
- Lithium Acetate-catalyzed Crossed Aldol Reaction between Aldehydes and Trimethylsilyl Enolates Generated from Other Aldehydes
- Lewis Base-catalyzed Diastereoselective Strecker-type Reaction between Trimethylsilyl Cyanide and Chiral Sulfinimines
- Lewis Base-catalyzed Diastereoselective Mannich-type Reaction between Ketene Silyl Acetals and Chiral Sulfinimines
- Lewis Base-catalyzed Trifluoromethylation of Aldimines with (Trifluoromethyl)trimethylsilane
- Stereoselective Synthesis of δ-Amino-β'-Hydroxy-β, γ-Unsaturated Esters by the Samarium(II) Iodide-mediated Aldol Reaction of Aldehydes with γ, δ-Aziridiny-α, β-Unsaturated Esters
- A New Method for the Synthesis of β-Amino-β'-Hydroxy Ketones by the Samarium(II) Iodide-mediated Aldol Reaction of Aldehydes with Aryl or Alkyl Aziridinyl Ketones
- Stereoselective Synthesis of 19-Hydroxytaxoid Using Intramolecular Pinacol Coupling Reaction
- Steroselective Construction of BC-ring unit of 19-Hydroxytaxol by Samarium(II) Iodide-mediated Double Aldol Cyclization
- Catalytic and β-Stereoselective Mannosylation of Several Glycosyl Acceptors with Mannosyl 6-Nitro-2-benzothiazoate
- Glycosyl 6-Nitro-2-benzothiazoate. A Highly Efficient Donor for β-Stereoselective Glycosylation
- Glycosyl fluoride : A superb glycosyl donor in glycosylation
- An Efficient Method for the Preparation of Chiral Mosher's Acid Analogues
- Convergent and Convenient Total Synthesis of Phytoalexin-Elicitor Active Heptasaccharide by One-Pot Sequential Glycosylation
- A Convenient Method for the Synthesis of β, γ-Unsaturated Amines from Alkenes via α, β-Unsaturated Diphenylsulfonium Salts
- Sulfenamide-catalyzed Oxidation of Primary and Secondary Alcohols with Molecular Bromine
- A Catalytic and α-Selective Sialylation Using Novel 5-Azido Sialy Fluoride
- Facile One-Pot Syntheses of Amidines and Enamines from Oximes via Beckmann Rearrangement Using Trifluoromethanesulfonic Anhydride
- Alkylation of α-Halo Diketones via Enol Phosphate Intermediate
- Lewis Base-catalyzed Strecker-type Reaction between Trimethylsilyl Cyanide and N-Tosylimines in Water-containing DMF
- One-pot Synthesis of β-Lactams from Aldimines and Ketene Silyl Acetals by Tandem Lewis Base-catalyzed Mannich-type Addition and Cyclization
- Efficient Method for the Esterification of Carboxylic Acids with Alcohols Using Di-2-thienyl Carbonate Promoted by Catalytic Amounts of DMAP and Hf(OTf)_4
- A New Method for the Lactonization of ω-Hydroxy Carboxylic Acids with Di-2-thienyl Carbonate by the Promotion of DMAP and Iodine
- Efficient Method for the Esterification of Carboxylic Acids with Alcohols Using Di-2-thienyl Carbonate Promoted by DMAP and Iodine
- A New Method for the Esterification of Carboxylic Acids with Various Alcohols by Using Di-2-thienyl Carbonate, a New Coupling Reagent
- Stereoselective Crossed Aldol Reaction via Boron Enolate Generated from α-Iodoketones and 9-BBN-H
- Lewis Base-Catalyzed Michael Reactions between Trimethylsilyl Enolate and α, β-Unsaturated Carbonyl Compounds
- Lithium Acetate-catalyzed Trifluoromethylation of Carbonyl Compounds with (Trifluoromethyl)trimethylsilane
- Lewis Base-catalyzed anti-Selective Mannich-type Reaction between Trimethylsilyl Enolates and Aldimines
- Product-catalyzed Mannich-type Reaction between Trimethylsilyl Enolates and N-Tosylaldimines
- Lithium Acetate-Catalyzed Aldol Reaction between Aldehyde and Trimethylsilyl Enolate in Anhydrous or Water-Containing N, N-Dimethylformamide
- Lithium Acetate-catalyzed Michael Reaction between Trimethylsilyl Enolate and α, β-Unsaturated Carbonyl Compound
- Lithium Acetate-catalyzed Mannich-type Reaction between Trimethylsilyl Enolates and Aldimines in a Water-containing DMF
- A Lewis Base-catalyzed Hetero Diels-Alder Reaction between Aldehydes and the Danishefsky's Diene
- Lewis Base-Catalyzed Mannich-type Reaction between Aldimine and Trimethylsilyl Enolate
- Sulfenamide Catalyzed Oxidation of Alcohols to the Corresponding Carbonyl Compounds with Anhydrous Chloramine-T
- Lithium Pyrrolidone Catalyzed Aldol Reaction between Aldehyde and Trimethylsilyl Enolate
- Preparation of Various Carboxylic Acid Esters from Bulky Alcohols and Carboxylic Acids by a New Type Oxidation-reduction Condensation Using 2, 6-Dimethyl-1, 4-benzoquinone
- Benzylation of Carboxylic Acids by Oxidation-Reduction Condensation Using Quinones and Benzyloxydiphenylphosphine
- A Convenient Method for the Preparation of Symmetrical or Unsymmetrical Ethers by The Coupling of Two Alcohols via A New Type of Oxidation-reduction Condensation Using Tetrafluoro-1, 4-benzoquinone
- Highly α-Stereoselective One-pot Sequential Glycosylation Using Glucosyl Thioformimidate Derivatives
- Friedel-Crafts Benzylation and Phenethylation Reactions Using Benzyl and Phenethyl Benzothiazol-2-yl Carbonate Derivatives
- Highly α-Selective Glycosylation with Glycosyl Acetate via Glycosyl Phosphonium Iodide
- Lithium Acetate-Catalyzed Aldol Reaction between Aldehyde and Trimethylsilyl Enolate
- Lewis Base Catalyzed Michael Reaction between Ketene Silyl Acetals and α, β-Unsaturated Carbonyl Compounds