Sulfenamide-catalyzed Oxidation of Primary and Secondary Alcohols with Molecular Bromine

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概要

• 論文の詳細を見る
• 2003-02-05

著者

• Mukaiyama Teruaki

  The Kitasato Institute Center For Basic Research

• Matsuo J

  Kitasato Inst. Tokyo

• Yamanaka Hiroki

  Department Of Chemistry And Materials Technology Kyoto Institute Of Technology

• MATSUO Jun-ichi

  The Kitasato Institute, Center for Basic Research

• Kawana Asahi

  Center For Basic Research Kitasato Institute

• KAWANA Asahi

  The Kitasato Institute, Center for Basic Research, TCI

• YAMANAKA Hiroyuki

  The Kitasato Institute, Center for Basic Research, TCI

• Yamanaka Hiroyuki

  Center For Basic Research Kitasato Institute

関連論文

• Cyanation of Alcohols with Diethyl Cyanophosphonate and 2,6-Dimethyl-1,4-benzoquinone by a New Type of Oxidation-Reduction Condensation
• Preparation of Nitriles from Primary Alcohols by a New Type of Oxidation-reduction Condensation Using 2, 6-Dimethyl-1, 4-benzoquinone and Diethyl Cyanophosphonate
• A Convenient Method for the Synthesis of Dialkyl Ethers by Alkylation of Alcohols Using Phosphinimidates in the Presence of a Catalytic Amount of Trimethylsilyl Triflate
• Lewis Base-Catalyzed [2,3]-Wittig Rearrangement of Silyl Enolates Generated from α-Allyloxy Carbonyl Compounds
• The Product-catalyzed [2,3]-Wittig Rearrangement of Silyl Enolates Generated from α-Allyloxy Ketones
• Ammonium Carboxylate-catalyzed [2,3]-Witting Rearrangement of Silyl Enolates Generated from α-Allyloxy Esters
• Ammonium Phenoxides-catalyzed syn-Selective Aldol Reaction Between an Aldehyde and an Trimethylsilyl Enolate
• Lewis Base-catalyzed [2, 3]-Wittig Rearrangement of Silyl Enolates Generated from α-Allyloxy Ketones
• Aldol Reaction of Enol Esters Catalyzed by Cationic Species Paired with Tetrakis(pentafluorophenyl)borate
• N-Arylation of Pyridin-2(1H)-ones with Pentavalent Organobismuth Reagents under Copper-Free Conditions
• An Efficient Synthesis of 3, 4-Dihydropyran-2-one Derivatives by Lewis Base-catalyzed Tandem Michael Addition and Lactonization
• Lithium Alkoxide-promoted Michael Reaction between Silyl Enolates and α, β-Unsaturated Carbonyl Compounds
• Trimethylaluminum-promoted 1,4-Addition Reaction of Cuprates to Six or Eight-membered 2-Hydroxymethyl Enones
• Stereospecific C-S Bond Formation from Chiral Tertiary Alcohols by Quinone-Mediated Oxidation-Reduction Condensation Using Alkyl Diphenylphosphinites and Its Application to the Synthesis of a Chiral Tertiary Thiol
• New methods for carbon–nitrogen, carbon–sulfur, and carbon–carbon bond formations by quinone-mediated oxidation–reduction condensation using alkyl diphenylphosphinites
• Convenient Methods for the Preparation of Unsymmetrical Double Aldols
• Trimethylsilyl Triflate Mediated New Carbon-Carbon Bond Forming Reactions between Benzyl Diphenylphosphinates and Organosilicon Compounds
• An Efficient Method for the Ether Forming Reaction between Alkyl Diphenylphosphinate and Alkoxytrimethylsilane by the Promotion of Trimethylsilyl Triflate
• Catalytic and Chemoselective Glycosylation between "Armed" and "Disarmed" Glycosyl p-Trifluoromethylbenzylthio-p-trifluoromethylphenyl Formimidates
• A Convenient Method for Carbon Extension of Acetals and Aldehydes by the Use of Ketenedithioacetal and Nucleophiles
• Efficient Method for the Preparation of Aromatic Bromides and Iodides by Ferrocenium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate-Catalyzed Halogenation with Bromine and Iodine Monochloride
• Zinc-Diethylaluminium Chloride Induced Coupling Reaction of Dibromofluoroacetate with Carbonyl Compounds. New Efficient and Selective Synthesis of α-Bromo-α-fluoro-β-hydroxy and α-Fluoro-β,β'-dihydroxy Esters
• A New Method for the Synthesis of Carboxylic Esters and Lactones with Di-2-thienyl Carbonate (2-DTC) by the Promotion of DMAP and Iodine
• Lewis Base-catalyzed Cyanomethylation of Aldimines with Trimethylsilylacetonitrile
• Highly Stereoselective Samarium(II) Iodide-Mediated Aldol Reactions of Acylaziridines with Aldehydes
• Highly trans-Selective Synthesis of β-Lactams by Tandem Phenoxide Anion-catalyzed Mannich-type Addition and Cyclization
• Efficient Method for the Lactonization of ω-Hydroxycarboxylic Acids with Di-2-thienyl Carbonate by the Promotion of Catalytic Amounts of DMAP and Hf(OTf)_4
• Enantioselective Synthesis of C11-C17 Segment of Mycinolide IV Using Samarium(II) Iodide-mediated Aldol Reaction
• A Facile One-Pot Benzylation of Sodium Enolates Using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide
• Stereoselective Synthesis of 19-Hydroxytaxoid by Utilizing Samarium(II) Iodide-Mediated Double Aldol Cyclization
• Lithium Acetate-catalyzed Crossed Aldol Reaction between Aldehydes and Trimethylsilyl Enolates Generated from Other Aldehydes
• Lewis Base-catalyzed Diastereoselective Strecker-type Reaction between Trimethylsilyl Cyanide and Chiral Sulfinimines
• Lewis Base-catalyzed Diastereoselective Mannich-type Reaction between Ketene Silyl Acetals and Chiral Sulfinimines
• Lewis Base-catalyzed Trifluoromethylation of Aldimines with (Trifluoromethyl)trimethylsilane
• Stereoselective Synthesis of δ-Amino-β'-Hydroxy-β, γ-Unsaturated Esters by the Samarium(II) Iodide-mediated Aldol Reaction of Aldehydes with γ, δ-Aziridiny-α, β-Unsaturated Esters
• Zinc-mediated Coupling Reaction of 2-Bromo-2, 3, 3, 3-tetrafluoropropanoate with Various Chiral Imines. Simple and Effective Access to Optically Active α-Fluoro-α-(trifluoromethyl)-β-amino Esters
• A Facile Synthesis of Various Fluorine-Containing Indole Derivatives via Palladium-Catalyzed Annulation of Internal Alkynes
• Highly Stereoselective Aldol-type Reaction of 2-Bromo-2, 3, 3, 3-tetrafluoropropanamide with Aldehydes Leading to erythro-α-Fluoro-α-(trifluoromethyl)-β-hydroxy Amides
• Highly Stereoselective Radical Reduction of α-Bromo-α-fluoro-β-hydroxy Esters with Tributyltin Hydride Leading to threo-α-Fluoro-β-hydroxy Esters
• Palladium-Catalyzed Coupling Reaction of Fluoroalkylated Propargyl Mesylates with Organozinc Reagents: Novel Synthesis of Optically Active Fluorine-Containing Trisubstituted Allenes
• New Synthetic Protocol with Trifluoro-1-propynylamines. An Efficient Access to α-(Trifluoromethyl)-δ-keto Amides via Hetero Diels-Alder Reaction
• A New Method for the Synthesis of β-Amino-β'-Hydroxy Ketones by the Samarium(II) Iodide-mediated Aldol Reaction of Aldehydes with Aryl or Alkyl Aziridinyl Ketones
• Stereoselective Synthesis of 19-Hydroxytaxoid Using Intramolecular Pinacol Coupling Reaction
• Steroselective Construction of BC-ring unit of 19-Hydroxytaxol by Samarium(II) Iodide-mediated Double Aldol Cyclization
• Oxidative Deamination of Various Primary Amines to the Corresponding Carbonyl Compounds by Using N-tert-Butylphenylsulfinimidoyl Chloride
• Oxidation of Various Secondary Amines to Imines with N-tert-Butylphenylsulfinimidoyl Chloride
• Catalytic and β-Stereoselective Mannosylation of Several Glycosyl Acceptors with Mannosyl 6-Nitro-2-benzothiazoate
• Glycosyl 6-Nitro-2-benzothiazoate. A Highly Efficient Donor for β-Stereoselective Glycosylation
• Glycosyl fluoride : A superb glycosyl donor in glycosylation
• Convergent and Convenient Total Synthesis of Phytoalexin-Elicitor Active Heptasaccharide by One-Pot Sequential Glycosylation
• Polymer-Supported Sulfinimidoyl Chlorides : A Convenient Reagent for Oxidation of Alcohols
• A Convenient Method for the Synthesis of β, γ-Unsaturated Amines from Alkenes via α, β-Unsaturated Diphenylsulfonium Salts
• A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts
• Sulfenamide-catalyzed Oxidation of Primary and Secondary Alcohols with Molecular Bromine
• A New Method for Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds by Using N-t-Butylbenzenesulfinimidoyl Chloride
• Polymer-supported Sulfinimidoyl Chloride as a Useful Reagent for Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds
• Catalytic Oxidation of Various Alcohols to the Corresponding Carbonyl Compounds with N-Chlorosuccinimide Using a Catalytic Amount of Sulfenamide
• Oxidation of Primary Alkyl Triflates to the Corresponding Aldehydes via Alkoxy(N-tert-butylamino)(methyl)sulfonium Triflates
• An Efficient Method for the p-Methoxybenzylation of Hydroxy Groups with 2-(4-Methoxybenzyloxy)-3-nitropyridine
• A Mild and Efficient Oxidation of Alcohols with N-tert-Butylphenylsufinimidoyl Chloride in the Coexistence of Zinc Oxide
• Benzylation of Alcoholic Hydroxyl Groups with Benzyl Mesylate by Using a Catalytic Amount of Lithium Tetrakis(pentafluorophenyl)borate in the Coexistence of Lithium Triflate and Magnesium Oxide
• A New and One-Pot Synthesis of α,β-Unsaturated Ketones by Dehydrogenation of Various Ketones with N-tert-Butyl Phenylsulfinimidoyl Chloride
• New Efficient Method for the Stereoselective Synthesis of α-(Trifluoromethyl)-α,β-unsaturated Amides. Lewis Acid-Catalyzed Reaction of 3,3,3-Trifluoro-1-propynylamine with Carbonyl Compounds
• A New Practical and Convenient Access to the Synthesis of N,N-Dialkyl-3,3,3-trifluoropropanamides
• Efficient and Convenient Route to (Z)-α, β-Unsaturated Difluoromethyl Ketones Based on the Reactio of 2, 3, 3-Trifluoro-1-tosyloxy-1-propenyllithium with Carbonyl Conpouneds
• Reactions of 1-Substituted-polyfluoro-1-propenyl p-Toluenesulfonates with Bifunctional Nitrogen Nucleophiles. A New Expedient Access to Monofluorinated Nitrogen Heterocycles^1
• Fluoride Ion-Promoted Reaction of Polyfluoro-1-propenyl p-Toluenesulfonate with Amines. Highly Efficient and General Access to (Z)-α-Fluoro-β-amino Acrylaldehydes
• A Catalytic and α-Selective Sialylation Using Novel 5-Azido Sialy Fluoride
• Facile One-Pot Syntheses of Amidines and Enamines from Oximes via Beckmann Rearrangement Using Trifluoromethanesulfonic Anhydride
• Lewis Base-catalyzed Strecker-type Reaction between Trimethylsilyl Cyanide and N-Tosylimines in Water-containing DMF
• One-pot Synthesis of β-Lactams from Aldimines and Ketene Silyl Acetals by Tandem Lewis Base-catalyzed Mannich-type Addition and Cyclization
• Efficient Method for the Esterification of Carboxylic Acids with Alcohols Using Di-2-thienyl Carbonate Promoted by Catalytic Amounts of DMAP and Hf(OTf)_4
• A New Method for the Lactonization of ω-Hydroxy Carboxylic Acids with Di-2-thienyl Carbonate by the Promotion of DMAP and Iodine
• Efficient Method for the Esterification of Carboxylic Acids with Alcohols Using Di-2-thienyl Carbonate Promoted by DMAP and Iodine
• A New Method for the Esterification of Carboxylic Acids with Various Alcohols by Using Di-2-thienyl Carbonate, a New Coupling Reagent
• Stereoselective Crossed Aldol Reaction via Boron Enolate Generated from α-Iodoketones and 9-BBN-H
• Lewis Base-Catalyzed Michael Reactions between Trimethylsilyl Enolate and α, β-Unsaturated Carbonyl Compounds
• Lithium Acetate-catalyzed Trifluoromethylation of Carbonyl Compounds with (Trifluoromethyl)trimethylsilane
• Lewis Base-catalyzed anti-Selective Mannich-type Reaction between Trimethylsilyl Enolates and Aldimines
• Product-catalyzed Mannich-type Reaction between Trimethylsilyl Enolates and N-Tosylaldimines
• Lithium Acetate-Catalyzed Aldol Reaction between Aldehyde and Trimethylsilyl Enolate in Anhydrous or Water-Containing N, N-Dimethylformamide
• Lithium Acetate-catalyzed Michael Reaction between Trimethylsilyl Enolate and α, β-Unsaturated Carbonyl Compound
• Lithium Acetate-catalyzed Mannich-type Reaction between Trimethylsilyl Enolates and Aldimines in a Water-containing DMF
• Sulfenamide Catalyzed Oxidation of Alcohols to the Corresponding Carbonyl Compounds with Anhydrous Chloramine-T
• Lithium Pyrrolidone Catalyzed Aldol Reaction between Aldehyde and Trimethylsilyl Enolate
• Benzylation of Carboxylic Acids by Oxidation-Reduction Condensation Using Quinones and Benzyloxydiphenylphosphine
• Highly α-Stereoselective One-pot Sequential Glycosylation Using Glucosyl Thioformimidate Derivatives
• Efficient and General Synthesis of Novel β-Polyfluoroalkoxy Vinamidinium Salts
• A Convenient Method for the Synthesis of α-Imidostyrenes from Styrenes and Imides via Diphenylstyrylsulfonium Salts
• Highly α-Selective Glycosylation with Glycosyl Acetate via Glycosyl Phosphonium Iodide
• Lewis Base Catalyzed Michael Reaction between Ketene Silyl Acetals and α, β-Unsaturated Carbonyl Compounds

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