Thermodynamics of Aluminum and Manganese Deoxidation Equilibria in Fe-Ni and Fe-Cr Alloys
スポンサーリンク
概要
- 論文の詳細を見る
Aluminum deoxidation equilibrium and manganese distribution have been studied at 1873 K in the equilibrium experiment between CaO-Al2O3 slags and Fe-10, 20, 40 and 60mass%Ni alloys or Fe-10, 20 and 40mass%Cr alloys containing Mn and Al. On the basis of these results, the effect of Ni or Cr on the activity coefficients of Al and Mn based on liquid iron is discussed and the interaction coefficient between Al and O in liquid iron has been estimated. Some experiments in which Fe-18mass%Cr-8mass%Ni alloy containing Al and Mn was equilibrated with CaO-Al2O3 slags have been carried out at 1 873 K. It was found that the observed values for the oxygen content and the Mn distribution ratio in Fe-18mass%Cr-8 mass%Ni alloy are in good agreement with the calculated values by using the activity coefficients of Al and Mn obtained in this study.
- 社団法人 日本鉄鋼協会の論文
- 2003-09-15
著者
-
Ohta Hiroki
Institute For Advanced Materials Processing Tohoku University
-
Suito Hideaki
Institute For Advanced Materials Processing Tohoku Unibersity
関連論文
- Effect of Oxide Catalyst on Heterogeneous Nucleation in Fe-10mass%Ni Alloys
- Quantitative Analysis of Total and Insoluble Elements and Inclusion Composition in Metal by Laser Ablation ICP-MS Method
- Analysis of Composition and Size Distribution of Inclusions in Fe-10Mass%Ni Alloy Deoxidized by Al and Mg Using Laser Ablation ICP Mass Spectrometry
- Analysis of Size Distribution of Inclusions in Metal by Using Single-particle Optical Sensing Method
- Measurement of Inclusion Size by Laser Ablation ICP Mass Spectrometry
- Thermodynamics on Control of Inclusions Composition in Ultra-clean Steels
- Effect of Sulfur and Oxygen on Engulfment and Pushing of Deoxidation Particles of ZrO_2 and Al_2O_3 during Solidification of Fe-10mass%Ni Alloy
- Dissolution Behavior and Stabilization of Fluorine in Secondary Refining Slags
- Effect of Particle Size Distribution on Austenite Grain Growth in Fe-0.05mass%C Alloy Deoxidized with Mn-Si, Ti, Mg, Zr and Ce
- Influence of Gypsum Addition and Hydrothermal Treatment on Dissolution Behavior of Fluorine in Hot Metal Pretreatment Slags
- Mechanism of Dephosphorization with CaO-SiO_2-Fe_tO Slags Containing Mesoscopic Scale 2CaO・SiO_2 Particles
- Precipitation and Dispersion Control of MnS by Deoxidation Products of ZrO_2, Al_2O_3, MgO and MnO-SiO_2 Particles in Fe-10mass%Ni Alloy
- Behavior of Phosphorous Transfer from CaO-Fe_tO-P_2O_5(-SiO_2) Slag to CaO Particles
- Refinement of Solidification Microstructure and Austenite Grain by Fine Inclusion Particles
- Effect of Nonrandomly Dispersed Particles on Austenite Grain Growth in Fe-10mass%Ni and Fe-0.20mass%C-0.02mass%P Alloys
- Fluorine-containing Mineral Phases in Ironmaking and Steelmaking Slags and Their Solubilities in Aqueous Solution
- Phosphorous Partition between 2CaO・SiO_2 Particles and CaO-SiO_2-Fe_tO Slags
- Effects of Dissolved Oxygen and Size Distribution on Particle Coarsening of Deoxidation Product
- Effects of N, C and Si Contents and MgO on Dispersion of TiN Particles in Fe-1.5%Mn-0.05(0.15)%C Alloy
- Dispersion Behavior of MgO, ZrO_2, Al_2O_3, CaO-Al_2O_3 and MnO-SiO_2 Deoxidation Particles during Solidification of Fe-10mass%Ni Alloy
- Effect of TiN Precipitates on Austenite Grain Size in Fe-1.5%Mn-0.12%Ti-Si(
- Effects of Oxide Particles and Solute Elements on Austenite Grain Growth in Fe-0.05mass%C and Fe-10mass%Ni Alloys
- Characteristics of Particle Size Distribution in Early Stage of Deoxidation
- Characteristics of Particle Size Distribution of Deoxidation Products with Mg, Zr, Al, Ca, Si/Mn and Mg/Al in Fe-10mass%Ni Alloy
- Thermodynamic Analysis of Slag Recycling Using a Slag Regenerator
- Dispersion of Primary Inclusions of Ce_2O_3 and CeS in Fe-0.20 mass%C-0.02 mass%P Alloy
- Effect of Primary Deoxidation Products orf AL_2O_3, ZrO_2, Ce_2O_3 and MgO on TiN Precipitation in Fe-10mass%Ni Alloy
- Thermodynamic Assessment of Hot Metal and Steel Dephosphorization with MnO-containing BOF Slags
- Thermodynamic Assessment of Manganese Distribution in Hot Metal and Steel
- Hydration of Crystallized Lime in BOF Slags
- Precipitation Behavior of Fe-Al-O Inclusions under Unidirectional Solidification of Fe-30mass%Ni Alloys Saturated with CaO-Al_2O_3 Slags
- Reoxidation of Aluminum in Liquid Iron with CaO-Al_2O_3-Fe_tO (≦3mass%) Slags
- Precipitation Behavior of Al-Ti-O-N Inclusions in Unidirectionally Solidified Fe-30mass%Ni Alloy
- Nitride Capacities in the CaO-base Ternary Slags at 1873K
- Liquid Phase Boundaries at 1873K in the Ternary CaO-Al_2O_3-MO_x(MO_x:MgO, ZrO_2) and CaO-SiO_2-MO_x(MO_x:TiO_2, MgO, Al_2O_3) Systems
- Activities in CaO-MgO_Al_2O_3 Slags and Deoxidation Equilibria of Al, Mg, and Ca
- Influence of Dissolved Cerium and Primary Inclusion Particles of Ce_2O_3 and CeS on Solidification Behavior of Fe-0.20mass%C-0.02mass%P Alloy
- Effect of dissolved Cerium on Austenite Grain Growth in an Fe-0.20mass%C-0.02mass%P Alloy
- Immobilization of Fluorine in Aqueous Solution by Calcium Aluminum Ferrite and the Mixture of Calcium Aluminate and Gypsum
- Immobilization of Hexavalent Chromium in Aqueous Solution through the Formation of 3CaO ・ (Al,Fe)_2O_3・ Ca(OH)_2/ xH_2O Phase, Ettringite and C-S-H Gel
- Thermodynamics of Aluminum and Manganese Deoxidation Equilibria in Fe-Ni and Fe-Cr Alloys
- Stabilization of Hexavalent Chromium in Solution by Mono-chromate, Ettringite and C-S-H Gel
- Effects of Calcium Hydroxide and Dicalcium Ferrite on Immobilization of Fluorine in Solution with Calcium Aluminates
- Calcium and Magnesium Deoxidation in Fe-Ni and Fe-Cr Alloys Equilibrated with CaO-Al_2O_3 and CaO-Al_2O_3-MgO Slags
- Effects of Calcium Silicates on Immobilization of Fluorine in Solution
- Austenite Grain Size Distribution and Topological Properties in Fe-0.09 to 0.53 mass%C-0.02 mass%P Alloys Containing Primary Inclusions of Ce_2O_3 and CeS
- Electrochemical Measurement of Critical Supersaturation in Fe-O__--M__- (M=Al, Si, and Zr)and Fe-O__--Al__--M__-(M=C, Mn, Cr, Si, and Ti)Melts by Solid Electrolyte Galvanic Cell
- Pinning of Austenite Grain Boundary of Fe-0.09 to 0.53 mass% C-0.02 mass%P Alloys by Primary Inclusions of Ce_2O_3 and CeS
- Leaching Behavior of Fluorine-containing Minerals in Seawater
- Magnesium Deoxidation and Nitrogen Distribution in Liquid Nickel Equilibrated with CaO-Al2O3-MgO Slags
- Precipitation Behavior of TiN in Fe-10mass%Ni Alloy during Solidification and Isothermal Holding at 1400℃