The Effect of Na_2O and Al_2O_3 on Dephosphorization of Molten Steel by High Basicity MgO Saturated CaO-FeO_x-SiO_2 Slag
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概要
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Highly basic CaO based slags saturated with MgO have been studied with respect to the phosphate capacity by measuring the phosphorous distribution ratio between slag and metal under controlled oxygen partial pressure at 1823 K and 1873 K. The effect of Na2O and Al2O3 addition and the activity of FeO and FeO1.5 were also determined. The phosphate capacity for MgO saturated CaO-FeOx-SiO2 slag containing 0 to 5 mass% Al2O3 and 0 to 1.75 mass% Na2O at 1873 K are in the range of 1018.37 to 1019.00 and that containing 4.1 to 5.0 mass% Al2O3 and 0 to 2.37 mass% Na2O at 1823 K are in the range of 1018.53 to 1018.62. For the slags containing 21.28 to 23.59 mass% Al2O3 and 0 to 4.25 mass% Na2O at 1823 K are in the range of 1017.84 to 1018.15.The addition of Na2O to the MgO saturated CaO-FeOx-SiO2 system increases the phosphate capacity of the slags. Alumina in the MgO saturated CaO-FeOx-SiO2 system decreases the phosphate capacity of the slags. The addition of Na2O to the MgO saturated CaO-FeOx-SiO2 system decreases the activity coefficients of FeO and FeO1.5 and those of P2O5. The activity coefficients of FeO and FeO1.5 show that they all behave as an acidic oxide in MgO saturated CaO-FeOx-SiO2 system.
- 2005-01-15
著者
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Tsukihashi Fumitaka
Department Of Advanced Materials Graduate School Of Frontier Science The University Of Tokyo
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Hamano Tasuku
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Li Guangqiang
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Li Guangqiang
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Tsukihashi Fumitaka
Department Of Advanced Materials Science Graduate School Of Frontier Sciences The University Of Toky
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Tsukihashi Fumitaka
Department Of Advanced Material Science The University Of Tokyo
関連論文
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