Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, γ-SiW_<10>{Fe(OH_2)}_2O_<38>^<6->, Including Radical-chain Mechanism
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概要
- 論文の詳細を見る
- 1998-12-05
著者
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Misono Makoto
Department Of Applied Chemistry Faculty Of Engineering The University Of Tokyo
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Mizuno Noritaka
Department Of Applied Chemistry Graduate School Of Egineering The University Of Tokyo
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Nozaki Chika
Department Of Applied Chemistry Graduate School Of Egineering The University Of Tokyo
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Misono Makoto
Department Of Applied Chemistry Graduate School Of Egineering The University Of Tokyo
関連論文
- Synthesis of Novel Layered Vanadyl Alkylphosphates as Catalyst Precursors for Selective Oxidation of n-Butane
- Migration of Copper Ions in Cu-MFI without Destruction of Zeolite Lattice or Dealumination upon Hydrothermal Treatment at 923K
- Microporous Heteropoly Compound as a Shape Selective Catalyst : Cs_H_PW_O_
- Selective Alkylation of p-Xylene with 2-Methylpropene by 12-Tungstophosphoric Acid
- Mobility and Exchange of Protons and Methanol Molecules in H_3PW_O_ Pseudoliquid Phase Detected by Solid State NMR
- Active crystal Face of Vanadyl Pyrophosphate for Catalytic Oxidation of n-Butane to Maleic Anhydride
- Alkylation of Isobutane with Butenes Catalyzed by a Cesium Hydrogen Salt of 12-Tungstophosphoric Acid
- Skeletal Isomerization of n-Butane Catalyzed by an Acidic Cesium Salt of 12-Tungstophosphoric Acid
- Novel Microstructures of Self-Assembled Microcrystallites of (NH_4)_3PW_O_ and Cs_3PW_O_
- Porous Aggregates of Unidirectionally Oriented(NH_4)_3PW_O_Microcrystallites : Epitaxial Self-Assembly
- Surface Acidity of Cesium Hydrogen Salts of 12-Tungstophosphoric Acid Characterized by Low-Temperature CO Adsorption
- In Situ Raman Spectroscopic Investigation of Surface Redox Mechanism of Vanadyl Pyrophosphate
- Origin of Microporosity of Ammonium Dodecatungstophosphate Unveiled by Single Crystal Structure Analysis
- Reaction of Nitrides of Molybdenum and Tungsten With Hydrogen Peroxide to Form Inorganic Proton Conductors
- Reaction of Tungsten Metal Powder with Hydrogen Peroxide to Form Peroxo Tungstates, An Useful Precursor of Proton Conductor
- Novel Formation of Nitrate and Ammonium Ions by Reaction of Inorganic Molybdenum Nitride with Hydrogen Peroxide
- Synthesis, Characterization, and Oxidation Catalysis of a Novel Dawson Polyoxometalate-supported Platinum(II) Complex, [{Pt(cod)}(P_2W_V_3O_)]^ (cod=1, 5-cyclooctadiene)
- Copper as an Effective Additive for Enhancement of Catalytic Activity of Cs_H_PVMo_O_ for Selective Oxidation of Lower Alkanes
- Selective Oxidative Dehydrogenation of Ethane Catalyzed by Cs_Mn_H_PVMo_O_ Catalyst Precursor
- The First Direct Detection of Rapid Migration of Acidic Protons between Heteropolyanions in H_3PW_O_・nH_2O (n
- The Hydrothermal Synthesis and Crystal Structure of (H_2O)[Ge_5O_10] and [(CH_3)_4N] [Ge_O_OH], Two Novel Porous Germanates
- Protocataltsis of H_3PW_O_-Choloophenol Decomposotion in Aqueous Media^
- Photocatalyzed Decomposition of 4-Chlorophenol by Keggin-Type Heteropolytungstate^#
- Catalytic Removal of Trimethylamine, an Offensive-Odor Component, by Selective Oxidative Decomposition to N_2, Co_2, and H_2O over Copper-Exchanged Zeolites
- Synthesis and Characterization of Water-Soluble, All-Inorganic Composition, Dawson-Type Trisubstituted Heteropolytungstates. Effect of Alkali Metal Countercations (Li, Na, K, and Cs) on the P_2W_Nb_3O_^ Polyoxoanion
- An Efficient One-pot Three-component Reaction to Produce 1,4-Disubstituted-1,2,3-triazoles Catalyzed by a Dicopper-substituted Silicotungstate
- Remarkable Effect of Manganese Center on Catalytic Activity for Decomposition of Hydrogen Peroxide
- Heterogeneously Catalyzed One-pot Synthesis of Aldimines from Primary Alcohols and Amines by Supported Ruthenium Hydroxides
- Tin-Tungsten Mixed Oxide as Efficient Heterogeneous Catalyst for Conversion of Saccharides to Furan Derivatives
- Essential Role of Acidity in the Catalytic Reduction of Nitrogen Monoxide by Methane in the Presence of Oxygen over Palladium-Loaded Zeolites
- Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, γ-SiW_{Fe(OH_2)}_2O_^, Including Radical-chain Mechanism
- Selective Synthesis of Secondary Amines via N-Alkylation of Primary Amines and Ammonia with Alcohols by Supported Copper Hydroxide Catalysts
- Remarkable Effect of Iron-Substitution for Molybdenum in Phosphododecamolybdate on Oxidative Dehydrogenation of 2-Propanol
- Hydrothermal Synthesis of Cubic Mesostructured Vanadium-Phosphorus Oxide
- Promotive Effects of the Addition of Alkaline Earth Metals to Ce-ZSM-5 Catalyst for the Reduction of Nitrogen Monoxide in the Presence of Propene and Oxygen
- Comparison of Catalytic Decomposition of Dinitrogen Oxide and Nitrogen Monoxide over Cu/ZSM-5 and Cu/Y Zeolites
- Catalytic Reduction of Nitrogen Monoxide by Methane over Palladium-Loaded Zeolites in the Presence of Oxygen
- Chemical Species Active for Selective Oxygenation of Methane with Hydrogen Peroxide Catalyzed by Vanadium-containing Compounds
- An Efficient Copper-mediated 1,3-Dipolar Cycloaddition of Pyrazolidinone-based Dipoles to Terminal Alkynes to Produce N,N-Bicyclic Pyrazolidinone Derivatives
- Cyclopropanation of Olefins with Diazo Compounds Catalyzed by a Dicopper-substituted Silicotungstate [γ-H_2SiW_O_Cu_2(μ-1,1-N_3)_2]^
- Structures and Sorption Properties of Ionic Crystals of Polyoxometalates with Macrocation
- Manganese Oxide-catalyzed Additive- and Solvent-free Aerobic Oxidative Synthesis of Primary Amides from Primary Amines
- Efficient Hydration of Nitriles Promoted by Simple Amorphous Manganese Oxide Using Reduced Amounts of Water
- Stereochemical studies of elimination reactions of 2-bromobutane and 2,3-dibromobutane over bivalent-ion exchanged silica gels.
- Stereochemical studies of elimination reactions of 2-bromobutane and 2,3-dibromobutane over alkali-ion exchanged silica gels.
- A Green Synthetic Route to Imides from Terminal Alkynes and Amides by Simple Solid Catalysts
- Effects of alkali metals added to silica-supported ruthenium catalysts on hydrogenation of carbon monoxide.
- Catalysis by heteropoly compounds. XII. Absorption properties of 12-tungstophosphoric acid and its salts.
- Catalysis by heteropoly compounds. XIII. An infrared study of ethanol and diethyl ether in the pseudoliquid phase of 12-tungstophosphoric acid.
- Catalytic properties of perovskite-type mixed oxides (ABO3) consisting of rare earth and 3d transition metals. The roles of the A- and B-site ions.
- Effects of addition of vanadium to alumina-supported ruthenium catalyst on adsorption and hydrogenation of carbon monoxide.
- Novel effects of K-addition to Ru/SiO2 on conversion of cyclohexane.
- Catalysis by heteropoly compounds. III. The structure and properties of 12-heteropolyacids of molybdenum and tungsten (H3PMo12-xWxO40) and their salts pertinent to heterogeneous catalysis.
- Catalytic properties of iron oxide. III. Oxidative dehydrogenation of butenes over iron oxide catalysts.
- The dehydrogenation of cyclohexane by the use of a porous-glass reactor.
- Catalytic properties of iron oxides. II. Isotopic exchange of oxygen, oxidation of carbon monoxide, and reduction-oxidation mechanism.
- Analysis of thermal desorption curves for heterogeneous surfaces. I. A linear variation of the activation energy of desorption.
- Stereospecific Dehydrobromination of dl- and meso-2,3-Dibromobutanes over Solid Catalysts
- The Catalytic Activity and Selectivity of Acidic Metal Salt Catalysts for n-Butene Isomerization
- Catalyst Isotope Effect in n-Butene Isomerization Catalyzed by Metal Sulfates
- Preparation of vanadium-phosphorus mixed oxide (P/V=1) catalysts and their application to oxidation of butane to maleic anhydride.