Improved Process for Hydrothermal Lead-Free Piezoelectric Powders and Performances of Sintered (K<sub>0.48</sub>Na<sub>0.52</sub>)NbO<sub>3</sub> Ceramics
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概要
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In this study, we report some improvements in a hydrothermal method for lead-free piezoelectric powders and the performance of the sintered (K<sub>0.48</sub>Na<sub>0.52</sub>)NbO<sub>3</sub> ceramics. To increase the obtained powder weight per source solution volume, the hydrothermal reaction conditions were modified. This improvement is important for mass production; however, it resulted in a larger particle size dispersion. Therefore, we examined to introduced the ball milling process that is useful for dense (K<sub>0.48</sub>Na<sub>0.52</sub>)NbO<sub>3</sub> ceramics. When a large amount of powder was obtained, it took a long time to eliminate the residual alkaline ions in the hydrothermal powders by a washing process. Therefore, a neutralization was conducted in the powder washing process. Using this powder, a solid solution of (K,Na)NbO<sub>3</sub> ceramics was synthesized. The relative density was successfully increased. Concerning the electrical properties, the relative permittivity was improved, and the piezoelectric constant $d_{33}$ was also increased from 114 to 130 pC/N.
- 2011-07-25
著者
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MAEDA Takafumi
Graduate School of Engineering, Hokkaido University
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Morita Takeshi
Graduate School of Engineering, Shizuoka University, Hamamatsu 432-8561, Japan
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Hemsel Tobias
Mechatronics and Dynamics, University of Paderborn, Fuerstenallee 11, 33102 Paderborn, Germany
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Hemsel Tobias
Mechatronics and Dynamics, University of Paderborn, 33102 Paderborn, Germany
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Morita Takeshi
Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa, Chiba 277-8563, Japan
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