ZnO Nanorod–TiO2-Nanoparticulate Electrode for Dye-Sensitized Solar Cells
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概要
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Highly dense ZnO nanorods were synthesized on TiO2-nanoparticulate coated fluorine-doped tin oxide (FTO) substrates by the chemical vapor deposition method for dye-sensitized solar cells (DSSCs). The uniformly grown ZnO nanorod layer has a thickness of ${\sim}4$ μm on the TiO2-nanoparticulate layer with a wurtzite structures as confirmed by the X-ray diffraction pattern. The DSSC fabricated with a ZnO nanorod/TiO2-nanoparticulate electrode had an overall light-to-electricity conversion efficiency $\eta$ of 3.7% with a short-circuit current density $J_{\text{SC}}$ of 8.12 mA/cm2, open-circuit voltage $V_{\text{OC}}$ of 0.76 V, and fill factor $\mathit{FF}$ of 0.59, whereas ZnO nanowire/TiO2-nanoparticulate-electrode-based DSSCs exhibited a low $\eta$ of 1.1% with $J_{\text{SC}}$ of 2.14 mA/cm2 and slightly high $V_{\text{OC}}$ of 0.79 V. It is expected that the enhanced photovoltaic performance of the ZnO nanorod/TiO2-nanoparticulate electrode can be attributed to high dye loading and high light harvesting through large surface areas of ZnO nanorods incorporated with TiO2-nanoparticulate as compared with the ZnO nanowire/TiO2-nanoparticulate electrode.
- 2009-12-25
著者
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Kim Tae-hong
Department Of Ceramic Engineering Yonsei University
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Lee Sang-kwon
Department Of Physiology College Of Medicine Pusan National University Medical Research Institute Pusan Medical University Hospital
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Hyung Jung-Hwan
Department of Semiconductor Science and Technology, SPRC, Chonbuk National University, Jeonju 561-756, Korea
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Lee Sang-Kwon
Department of Semiconductor Science and Technology, SPRC, Chonbuk National University, Jeonju 561-756, Korea
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Akhtar M.
Department of Semiconductor Science and Technology, SPRC, Chonbuk National University, Jeonju 561-756, Korea
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Yang O-Bong
School of Chemical Engineering, Chonbuk National University, Jeonju 561-756, Korea
関連論文
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