Photocrosslinking of Blends of Multifunctional Diphenylfluorene Derivatives and Polysilanes Using Visible Light
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概要
- 論文の詳細を見る
We have devised the photocrosslinked films of diphenylfluorene and polysilanes blends on irradiation at 405 nm. Photo-decomposition of Si-Si bonds of polysilanes was successfully suppressed during irradiation of the visible light. The photocrosslinking properties were strongly affected by PEB conditions and irradiation dose. The sensitivity of PMPS/BCAFG blended film was superior to that of hb-PPS/BCAFG blended one. The photocrosslinking was mainly due to the acid-catalyzed polymerization of the epoxy moieties of BCAFG. PMPS and hb-PPS moieties were incorporated with the film by the termination reaction of the polymerization with the terminal OH groups.
- The Society of Photopolymer Science and Technology (SPST)の論文
著者
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Okamura Haruyuki
Department Of Applied Chemistry Graduate School Of Engineering Osaka Prefecture University
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Matsumoto Akikazu
Department Of Applied And Bioapplied Chemistry Graduate School Of Engineering Osaka City University
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Miyauchi Shinsuke
Fine Chemicals Development Center, Osaka Gas Chemicals Co., Ltd.
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Funamoto Kenji
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University
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Minokami Keiko
Fine Chemicals Development Center, Osaka Gas Chemicals Co., Ltd.
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