Kinetic Analysis on the Ignition of PRF Mixtures with Consideration of Cross-Reactions
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概要
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Backwards reaction tracking method proposed by the authors was applied to define the cross reactions. When alkane and alkane are mixed, RO<SUB>2</SUB>+R'·RO+R'O and RO<SUB>2</SUB>+R'O<SUB>2</SUB>·RO+R'O+O<SUB>2</SUB> was found to be the possible cross-reactions. In alkane-alkane mixture, however, the influence of these cross reactions is negligible. Chemical kinetics of nC<SUB>7</SUB>H<SUB>16</SUB> - iC<SUB>8</SUB>H<SUB>18</SUB> mixture was analyzed. When the portion of iC<SUB>8</SUB>H<SUB>18</SUB> is increased, ignition delay until LTO, τ<SUB>1</SUB>, increased, and ignition delay from LTO to thermal ignition, τ<SUB>2</SUB>, decreased and temperature at the end of LTO, T<SUB>LTO</SUB> decreased. By replacing iC<SUB>8</SUB>H<SUB>18</SUB> with N<SUB>2</SUB>, it was clarified, that iC<SUB>8</SUB>H<SUB>18</SUB> addition prevents 2-step OH reproducing paths causes longer τ<SUB>1</SUB>, and higher T<SUB>LTO</SUB> causes longer τ<SUB>2</SUB>.
- 公益社団法人 自動車技術会の論文
公益社団法人 自動車技術会 | 論文
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