電極酸化反応によるケイ素の脱離を伴わないアリールシラン類のシアノ化反応
スポンサーリンク
概要
- 論文の詳細を見る
The electrochemical oxidation of ortho- and meta-anisylsilanes in the presence of sodium cyanide facilitated the direct cyanation of the aromatic ring through the exchange of a hydrogen atom and a cyano group to give cyanoanisylsilanes without elimination of the silyl group. The anodic cyanation of anisylsilanes in methanol and electrophilic reactions of the obtained cyanoanisylsilanes largely depended on the substituted position of the silyl group on the aromatic ring and on the bulkiness of the alkyl group on the silicon atom.
著者
-
Yamaguchi Atsushi
Faculty Of Engineering Himeji Institute Of Technology
-
Maekawa Hirofumi
Department Of Chemistry Faculty Of Engineering Nagaoka University Of Technology
-
YAMAGUCHI Atsushi
Faculty of Engineering, Osaka Institute of Technology
-
NAKAMURA Tatsuya
Faculty of Engineering, Osaka Institute of Technology
関連論文
- Preparation of a Decagonal Al-Cu-Co Single Quasicrystal by the Czochralski Method
- Catalytic Electrosynthesis in Ionic Liquid : Performance of Nickel-(2,2'-Bipyridine) Complexes for Production of Aryl Propan-2-ones
- Studies on the Characteristics of Axial Plunger Pumps and Motors : 2nd Report, Ripples in Oil Hydraulic Systems Composed of the Pump and the Motor
- 硝酸ラジカルをメディエ-タ-に用いた第1級アルコ-ルの間接陽極酸化
- Cavitation in an Axial Piston Pump
- Practical Synthesis of Diethyl Phenylsuccinate by Mg-promoted Carboxylation of Ethyl Cinnamate
- Oxidation of Ethers by NO_3・Generated from NO_3^--with Anodic Oxidation
- Phase Transition and Magnetic Properties of Supercooled Al-Ge-TM(TM=Cr, Fe, Co)Alloys
- Stereoselectivity in Intramolecular Cyclization of Non-conjugated Unsaturated Ketones by Electroreduction
- REAL K-COHOMOLOGY OF COMPLEX PROJECTIVE SPACES
- Mg-Promoted Stereoselective Desulfonation of β-Arylvinyl Sulfone Derivatives
- Mg-Promoted Regioselective Carbon-Silylation of α-Phosphorylacrylate Derivatives
- Highly Stereo- and Regio-Selective Intramolecular Cyclization with Diastereoselective Asymmetric Induction by Electroreduction of Optically Active N-Alkenyl-2-Acylpyrrolidines
- 芳香族ビニル及びイミノ誘導体の電極還元反応によるN-カルボアルコキシイミダゾールによるワンポットビシナル及びジェミナル二重カルボアルコキシ反応
- 電極酸化反応によるケイ素の脱離を伴わないアリールシラン類のシアノ化反応
- Stereoselective Synthesis of Spiro-Lactones Possessing Cyclopropane Rings through Electroreductive Cross Coupling of Styrene Derivatives with Diphenyl Succinate or Glutarate