Stereoselective Synthesis of Spiro-Lactones Possessing Cyclopropane Rings through Electroreductive Cross Coupling of Styrene Derivatives with Diphenyl Succinate or Glutarate
スポンサーリンク
概要
- 論文の詳細を見る
Electroreduction of α-alkylated styrenes (1) in the presence of diphenyl succinate (2) or glutarate (3) in N,N-dimethylformamide (DMF) using an undivided cell equipped with Zn plates as the anode and the cathode brought about regio- and stereoselective efficient double carbon-carbon bond formation between the two olefinic carbon atoms of 1 and one carbonyl carbon atom of 2 or 3, followed by lactonization to give the corresponding five- (4) or six-membered spiro-lactones (5) possessing cyclopropane rings in moderate to good yields.
- 公益社団法人 電気化学会の論文
著者
-
Yamamoto Yoshimasa
Department Of Applied Biosciences Graduate School Of Agriculture Kyoto University
-
Dhiman Anand
Department Of Chemistry Nagaoka University Of Technology
-
Kendrekar Pravinkumar
Department Of Chemistry Nagaoka University Of Technology
-
Maekawa Hirofumi
Department Of Chemistry Faculty Of Engineering Nagaoka University Of Technology
-
Nishiguchi Ikuzo
Department of Chemical Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188, Japan
関連論文
- コハク酸ジフェニル又はグルタル酸ジフェニルとスチレン誘導体の電極還元法を用いるクロスカップリングによるシクロプロパン環を有するスピロラクトン類の立体選択的合成
- PJ-720 Remodeling of Atrial Fibrillation-Ishchmia of the Atria?-(Arrhythmia, basic-6 (A) PJ121,Poster Session (Japanese),The 70th Anniversary Annual Scientific Meeting of the Japanese Circulation Society)
- The formation and degradation of cyanobacterium Aphanizomenon flos-aquae blooms : the importance of pH, water temperature, and day length
- Importance of interspecific competition in the abundance of Aphanizomenon flos-aquae (Cyanophyceae)
- Catalytic Electrosynthesis in Ionic Liquid : Performance of Nickel-(2,2'-Bipyridine) Complexes for Production of Aryl Propan-2-ones
- 硝酸ラジカルをメディエ-タ-に用いた第1級アルコ-ルの間接陽極酸化
- Practical Synthesis of Diethyl Phenylsuccinate by Mg-promoted Carboxylation of Ethyl Cinnamate
- Oxidation of Ethers by NO_3・Generated from NO_3^--with Anodic Oxidation
- Stereoselectivity in Intramolecular Cyclization of Non-conjugated Unsaturated Ketones by Electroreduction
- Mg-Promoted Stereoselective Desulfonation of β-Arylvinyl Sulfone Derivatives
- Mg-Promoted Regioselective Carbon-Silylation of α-Phosphorylacrylate Derivatives
- Prevalence of fecal carriage of extended-spectrum β-lactamase-producing Enterobacteriaceae among healthy adult people in Japan
- Highly Stereo- and Regio-Selective Intramolecular Cyclization with Diastereoselective Asymmetric Induction by Electroreduction of Optically Active N-Alkenyl-2-Acylpyrrolidines
- Mechanical properties and cross-linking structure of cross-linked natural rubber
- 芳香族ビニル及びイミノ誘導体の電極還元反応によるN-カルボアルコキシイミダゾールによるワンポットビシナル及びジェミナル二重カルボアルコキシ反応
- Chemical Properties of a Perfluoropolyether Lubricant with Functional Groups of Pentafluorobenzyl on Hard Disk Media
- 電極酸化反応によるケイ素の脱離を伴わないアリールシラン類のシアノ化反応
- Stereoselective Synthesis of Spiro-Lactones Possessing Cyclopropane Rings through Electroreductive Cross Coupling of Styrene Derivatives with Diphenyl Succinate or Glutarate