Electrochemical Oxidation of 1,2-Diols to α-Hydroxyketones in Water

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概要

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• An environmentally friendly electrochemical process for selective oxidation of 1,2-diols in water using Me2SnCl2 catalyst, KBr as a bromide ion source and platinum electrodes has been developed. This method uses "Br+" ion, generated at the anode as an oxidant and OH− ion, at the cathode as an electro-generated base. Various cyclic and acyclic 1,2-diols were tolerated affording the corresponding α-hydroxyketones in moderate to high yields.

• 公益社団法人 電気化学会の論文

著者

• Onomura Osamu

  Graduate School Of Biomedical Sciences Nagasaki Univ. 1-14 Bunkyo-machi Nagasaki 852-8521 Jpn

• Kuriyama Masami

  Graduate School of Biomedical Sciences, Nagasaki University

• WILLIAM Julius

  Graduate School of Biomedical Sciences, Nagasaki University

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• Electrochemical Oxidation of 1,2-Diols to α-Hydroxyketones in Water

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