One-Pot Synthesis of Phenol Derivatives by the Novel Intramolecular Alder–Rickert Reaction : Effects of Aryl Substituent at the 3-Position of Cyclohexenone Derivatives on Reactivity
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概要
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We examined In(OTf)3-catalyzed enolization and intramolecular Alder–Rickert reactions of cyclohexenone derivatives. The 3-aryl substituted cyclohexenone derivatives bearing an ethoxycarbonyl-substituted alkyne moiety could be converted into the corresponding phenols in comparatively good yield.
- 公益社団法人 日本薬学会の論文
著者
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Miyaoka Hiroaki
School Of Pharmacy Tokyo University Of Pharmacy And Life Science
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Kinbara Atsushi
School of Pharmaceutical Sciences, Ohu University
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Yamagishi Takehiro
School of Pharmaceutical Sciences, Ohu University
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Fujishige Takeshi
School of Pharmacy, Tokyo University of Pharmacy and Life Sciences
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- One-Pot Synthesis of Phenol Derivatives by the Novel Intramolecular Alder–Rickert Reaction : Effects of Aryl Substituent at the 3-Position of Cyclohexenone Derivatives on Reactivity