Enhancement of Toluene Formation by Water during Electrolysis of Chlorobenzene at Pt Electrode in Acetonitrile
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概要
- 論文の詳細を見る
Chlorobenzene was electrolyzed on polycrystalline platinum electrode in acetonitrile with various water concentrations at −3.02 V(vs. Fc/Fc+). Formation rate of the reduction products depend on water concentration remarkably. Benzene is a main product at [H2O]≤0.3 mol dm−3. At [H2O]≥0.35 mol dm−3, toluene is obtained as well as benzene. Partial current density of toluene gives maximum at [H2O]=0.44 mol dm−3. Formation of toluene closely relates with production of methane resulting from the decomposition of acetonitrile.
- 公益社団法人 電気化学会の論文
著者
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Hoshi Nagahiro
Department Of Applied Chemistry And Biotechnology Graduate School Of Engineering Chiba University
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NAKAMURA Masashi
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University
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HARADA Toshihiro
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University
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NOZU Daiki
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University
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NOZU Daiki
Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University
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