Difference of the Final Products of the Photochemical Reactions of Azanaphthalenes and Naphthalene in Mixed Crystals of Durene.
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概要
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Final products of the photochemical reactions of quinazoline, quinoline, and naphthalene in 1,2,4,5-tetramethylbenzene (durene) mixed crystals are investigated on the basis of the phosphorescence and fluorescence spectra of the products. Quinazoline in durene is considered to transform into a benzene derivative, whereas naphthalene and quinoline tranform into anthracene derivatives. These products are different from a pyrazine derivative found in the case of quinoxaline, which is specific to the reaction in a durene mixed crystal. The cause of this difference is discussed in terms of the configurations of guests in the mixed crystals and the difference of the molecular structures.
- 公益社団法人 日本化学会の論文
著者
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Hoshi Nagahiro
Department Of Applied Chemistry And Biotechnology Graduate School Of Engineering Chiba University
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Hirota Noboru
Department Of Chemistry Faculty Of Science Kyoto University
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HOSHI Nagahiro
Department of Applied Chemistry, Faculty of Engineering, Chiba University
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Yamauchi Seigo
Chemical Research Institute of Non-Aqueous Solutions, Tohoku University
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