Structural Modification of Segmented-in-series Tubular SOFCs Using Performance Simulation and the Effect of (Sm, Ce)O2 Cathode Interlayer on the Generation Characteristics under Pressurization
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概要
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To improve the segmented-in-series tubular SOFC performance operating at 1173 K, we studied cathode interlayer (CIL) and a structural modification of the cell stack using a performance simulation. As the result of changing CIL into (Ce0.8Sm0.2)O2 (SDC20) (type 2) from La0.7Sr0.3MnO3-YSZ (type 1), ohmic polarization (ηIR) and activation/concentration polarizations (ηA+ηC) of type 2 decreased 16% and 47% than those of type 1, respectively. Next, based on the simulation results of ηIR, a tubular SOFC (type 4) with structural modification in the length ratio of the effective generation part (EGP) and interconnector part (ICP) was fabricated by applying SDC20 to CIL. Ohmic polarization of type 4 decreased 52% than that of type 2, while ηA+ηC increased 63%. However, the generation performance of type 4 improved than that of type 2, since ηIR decreased more than the increase of ηA+ηC. In a pressurized test of type 4, an increase of pressure resulted in a decrease of the area specific resistance calculated from the inclination of I-V characteristics including EGP and ICP resistances. In a durability test of type 4 conducted for 7000 h in atmospheric pressure, a degradation rate of 0.73% 1000 h−1 was obtained.
著者
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Hisatome Nagao
Nagasaki Shipyard And Machinery Works Mitsubishi Heavy Industries Ltd.
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Tomida Kazuo
Nagasaki Shipyard And Machinery Works Mitsubishi Heavy Industries Ltd.
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Kabata Tatsuo
Nagasaki Shipyard And Machinery Works Mitsubishi Heavy Industries Ltd.
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Tsukuda Hiroshi
Nagasaki Research And Development Center Mitsubishi Heavy Industries Ltd.
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Yamazaki Yohtaro
Department Of Electronic Chemistry Interdisciplinary Graduate School Of Science And Engineering Toky
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