Pulsed Neutron Diffraction Study of NaNO2 and KNO2 Pure Melts
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概要
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The short-range structural parameters for NaNO2 and KNO2 pure melts were determined by the time-of-flight neutron diffraction. The precise analyses of structural parameters obtained such as coordination number, interatomic distance, and temperature factor allowed us to conclude that (1) there exist stable NO2− anions in the melts, (2) NO2− anions behave like NO3− anions due to the existence of lone pairs of electrons, (3) the short-range structure of KNO2 pure melt is similar to that of NaNO2 pure melt but the cation site relative to anion is a little different from each other in terms of the cation size effect.
- 公益社団法人 電気化学会の論文
著者
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FUKUNAGA Toshiharu
Research Reactor Institute, Kyoto University
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Itoh Keiji
Research Reactor Institute Kyoto University
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Fukunaga Toshiharu
Research Reactor Institute Kyoto University
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Misawa Masakatsu
High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801, Japan
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ITOH Keiji
Research Reactor Institute, Kyoto University
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OHKUBO Takahiro
AIST
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IWADATE Yasuhiko
Graduate School of Engineering, Chiba University
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HARADA Takumi
Graduate School of Engineering, Chiba University
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FUKUSHIMA Kazuko
Formerly of Chiba University
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MISAWA Masakatsu
High Energy Accelerator Research Organization (KENS)
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