Numerical Analysis of Ionic Mass Transfer Phenomena Accompanying Electrochemical Reactions in PC and Ionic Liquid
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概要
- 論文の詳細を見る
The transient mass transfer rate of Li+ ion caused by the electrochemical deposition and dissolution of Li metal in propylene carbonate (PC) and ionic liquid (IL) containing a lithium salt is numerically analyzed. The previous mesurements of transport properties such as diffusion coefficient of a lithium salt and electrolyte viscosity are used in the present calculation. The concentration profile of Li+ ion developed along electrode surface has been in-situ measured by holographic interferometry. The measurement values are reasonably compared with the calculations except for the apparent incubation period observed in the initial stage of electrochemical deposition and dissolution.
- 公益社団法人 電気化学会の論文
著者
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Kida Shigeo
Department Of Mechanical Engineering And Science Kyoto University
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Kawai Shunsuke
Department of Cardiology, Nagano Chuo Hospital
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KAWAI Shunsuke
Department of Mechanical Engineering and Science, Kyoto University
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NISHIKAWA Kei
Laboratorie de Physique de la Matiere Condensee, Ecole Polytechnique
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FUKUNAKA Yasuhiro
Nano Technology Research Center, Waseda University
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- Numerical Analysis of Ionic Mass Transfer Phenomena Accompanying Electrochemical Reactions in PC and Ionic Liquid