炭素源がリチウム過剰Li.TiO炭素複合体の表面形態と電気化学的特性に及ぼす影響
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概要
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We have investigated the preparation and electrochemical characteristics of a lithium excess Li4.3Ti5O12 carbon composite (Li4.3Ti5O12/C) with different carbon sources (polyacryl acid, polyvinyl alcohol, and carboxy methyl cellulose sodium). We have prepared the lithium excess Li4.3Ti5O12/C by a spray-drying method followed by calcining at 800°C in a nitrogen atmosphere. The TEM observations indicated that the surface of the Li4.3Ti5O12/C particle was clearly covered with an amorphous carbon layer. The Li4.3Ti5O12/C materials employing polyvinyl alcohol as the carbon source showed the best rate performance with the highest discharge capacity of 117 mAh (g-Li4.3Ti5O12/C)−1 at the 10C rate.
- 公益社団法人 電気化学会の論文
著者
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Kadoma Yoshihiro
Department Of Applied Chemistry Tokyo Institute Of Technology
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Kumagai Naoaki
Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwate University
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Yoshikawa Daisuke
Department Of Anesthesiology And Reanimatology Gunma University School Of Medicine
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UI Koichi
Department of Industrial Chemistry, Faculty of Science and Technology, Tokyo University of Science
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CHIBA Yusuke
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University
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MITOBE Yuko
Technical Division, Iwate University
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UI Koichi
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University
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KADOMA Yoshihiro
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University
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UI Koichi
Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate University
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YOSHIKAWA Daisuke
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University
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