電位差測定法による酸のイオン対生成定数の測定と無水エチレンジアミンおよび水中での酸の相対強度〔英文〕
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The ion-pair association constants of acids were determined from potentiometrical data obtained with the platinized platinum hydrogen electrode and saturated zinc chloride-zinc amalgam reference electrode. The investigation was also made in order to evaluate the behavior of acids in ethylene-diamine and to determine the acidity relationship between ethylenediamine and water solvents. The following relationship has been determined empirically: Below (pK<SUB>a</SUB>)<SUB>H2O</SUB>=7.0, (pK<SUB>a</SUB>)<SUB>en</SUB>=3.9; Above (pK<SUB>a</SUB>)<SUB>H2O</SUB>=7.0, (pK<SUB>a</SUB>)<SUB>en</SUB>= {3.9+(pK<SUB>a</SUB>)<SUB>H2O</SUB>}-7.0
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- 電位差測定法による酸のイオン対生成定数の測定と無水エチレンジアミンおよび水中での酸の相対強度〔英文〕
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