An alternative method of solving the rose-drago equation for the determination of equilibrium constants of molecular complexes.

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概要

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• An alternative method for solving the Rose-Drago equation for the determination of equilibrium constants of molecular complexes has been developed. It yields well-defined <I>K</I> values even for certain systems in which the Rose-Drago procedure for solving the R-D equation is not satisfactory. Our method is based on the transformation of the Rose-Drago equation into one involving three variables and using two linear plots. In applying the method to a wide variety of experimental data, the calculated values of the equilibrium constant have been found to be in excellent agreement with those computed by the well-known iterative procedure. With good data, the calculated values are in good agreement with those from the Benesi-Hildebrand or some other modified plots.

• 公益社団法人 日本化学会の論文

著者

• Mukherjee Dulal

  Department of Chemistry, University College of Science and Technology

• Seal Bejoy

  Department of Chemistry, Burdwan University

• Mukherjee Ashok

  Department of Chemistry, Burdwan University

• Mukherjee Ashok

  Department of Chemical Engineering, Indian Institute of Science

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