A method for independent determination of equilibrium constant and molar absorptivity of molecular complexes from spectrophotometric data.

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概要

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• Two separate equations, one cubic in <I>K</I> and the other quadratic in ε, have been developed for calculating <I>K</I> and ε of molecular complexes independently of each other. The equations on testing with various spectrophotometric data yielded values of <I>K</I> and ε which agree with those obtained by others using well known procedures.

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著者

• Mukherjee Dulal

  Department of Chemistry, University College of Science and Technology

• Seal Bejoy

  Department of Chemistry, Burdwan University

• Sil Harideb

  Department of Chemistry, Burdwan University

• Banerjee Manas

  Department of Chemistry, Burdwan University

• Mukherjee Dulal

  Department of Chemistry, University of Calcutta

関連論文

• Reaction Kinetics in a Microemulsion Medium IV. Hexacyanoferrate(III)-Iodide Reaction in Water/Aerosol-OT/Heptane Microemulsion and Mixed Solvents
• A method for independent determination of equilibrium constant and molar absorptivity of molecular complexes from spectrophotometric data.
• A new method for the determination of equilibrium constant and molar extinction coefficient of 1:1 type complex.
• An alternative method of solving the rose-drago equation for the determination of equilibrium constants of molecular complexes.

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