The dissociation rate of S2 produced from COS pyrolysis.
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概要
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The disappearance rate of S<SUB>2</SUB>, which was produced from the pyrolysis of COS, was measured behind incident shock waves by monitoring the UV emission in the temperature range of 4500–6000 K and in the pressure range of 0.32–0.5 atm. It was found that two processes could possibly account for the disappearance of S<SUB>2</SUB>:<BR>S_2+Ar→2S+Ar\tag3<BR>and<BR>(<U>Remark: Graphics omitted.</U>)<BR>and the following rate equation was obtained:<BR>-d[S_2]/dt=k_II[S_2][Ar]mol cm^-3s^-1<BR>where<BR>k_II=10^13.68exp(-77kcal/RT)cm^3mol^-1s^-1.
著者
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Saito Ko
Department Of Chemistry Graduate School Of Science Hiroshima University
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Murakami Ichiro
Department Of Electrical Engineering Faculty Of Eng. Yokohama National Univ.
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Higashihara Tetsuo
Department of Chemistry, Faculty of Science, Hiroshima University
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Murakami Ichiro
Department of Chemistry, Faculty of Science, Hiroshima University
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