The thermal decomposition of CF3I in Ar.

スポンサーリンク

概要

• 論文の詳細を見る

• The thermal decomposition of CF<SUB>3</SUB>I behind reflected shock waves was studied by means of the UV absorption over the temperature range of 935–1235 K and in the density range of 6.3×10<SUP>−6</SUP>–3.8×10<SUP>−6</SUP> mol cm<SUP>−3</SUP>. The decomposition rate was in the fall-off region, and the main process was the C-I bond fission. The rate constants corresponding to the limiting high- and low-pressure regions were determined to be;<BR><I>k</I><SUB>∞</SUB>=10<SUP>14.67</SUP>exp(−27200⁄<I>T</I>)s<SUP>−1</SUP><BR>and;<BR><I>k</I><SUB>0</SUB>⁄[Ar]=10<SUP>14.71</SUP>exp(−15000⁄<I>T</I>)cm<SUP>3</SUP>mol<SUP>−1</SUP>s<SUP>−1</SUP>.

• 公益社団法人 日本化学会の論文

著者

• Saito Ko

  Department Of Chemistry Graduate School Of Science Hiroshima University

• Tahara Hiroyuki

  Department Of Cardiology Matsue Red Cross Hospital

• Murakami Ichiro

  Department Of Electrical Engineering Faculty Of Eng. Yokohama National Univ.

• Yoneda Yuji

  Department of Chemistry, Faculty of Science, Hiroshima University

• Kidoguchi Sadao

  Department of Chemistry, Faculty of Science, Hiroshima University

• Murakami Ichiro

  Department of Chemistry, Faculty of Science, Hiroshima University

関連論文

• Comparison of 2D- and 3D- intravascular ultrasound (IVUS) assessments of neointimal hyperplasia of in-stent restenosis
• Relation between Pre-Interventional Neointimal Hyperplasia Burden of In-Stent Restenosis and Chronic Amount of Neointimal Proliferation : A Volumetric Intravascular Ultrasound Study
• Influence of Smoking on Angiographic Restenosis after Percutaneous Coronary Intervention
• The Efficacy of IVUS Guided Stenting for Long Lesion
• Results of the stent versus directional coronary Atherectomy for proximal left anterior descending artery
• Provisional stenting following percutaneous thrombectomy for patients with acute myocardial infarction
• Cynomolgus Monkey Embryonic Stem Cell Lines Express Green Fluorescent Protein(CELL AND TISSUE ENGINEERING)
• Influences of the preventive use of antifilarial drugs on the transmission of dirofilaria immitis in house-dogs in Nagasaki city, Japan
• Association of Lifestyle with Physical and Mental Health in Japanese Radiological Technologists
• 0824 Comparison of thallium-201 uptake with technetium-99m-tetrofosmin uptake for early and late assessment of myocardial viability after direct PTCA for acute myocardial infarction
• IS-21 Prognosis of intestinal perforation in the extremely low birth weight infants(International Session IV)
• Cervico-Mediastinal Bronchogenic Cyst Occurring in the Prenatal Period : Report of a Case
• Modulated differentiation of embryonic stem cells into hepatocyte-like cells by coculture with hepatic stellate cells(CELL AND TISSUE ENGINEERING)
• Development of a Work Improvement Checklist for Occupational Mental Health Focused on Requests from Workers
• A Malignant Rhabdoid Tumor of the Kidney Occurring Concurrently with a Brain Tumor : Report of a Case
• Spontaneous Rupture of the Stomach in Preschool Age Children:A Report of Two Cases
• Giant Mediastinal Lymphangioma in a Neonate : Report of a Case
• Assignment of the C K-Shell Photoabsorption Spectrum of CF_3CN Molecule
• The Conformation of 1-Alkyl-2-phenylpropan-1-ols Studied by Ab Initio MO Calculations. Relevance of the CH/π and OH/π Hydrogen Bonds
• General Preference for Alkyl/Phenyl Folded Conformations. Relevance of the CH/π and CH/O Interactions to Stereochemistry as Evidenced by Ab Initio MO Calculations
• The Conformation of 2-Phenylpropionaldehyde and Alkyl 1-Phenylethyl Ketones as Evidenced by Ab Initio Calculations. Relevance of the CH/π and CH/O Interactions in Stereochemistry^__
• Hydrogen-Bond-Like Nature of the CH/π Interaction as Evidenced by Crystallographic Database Analyses and Ab Initio Molecular Orbital Calculations
• An Efficient Method for Determining Population Decay of Nonadiabatic Unimolecular Reactions
• POLYPOID COLONIC HAMARTOMATOUS INVERTED POLYP
• Synthetic Models of Earth's Storms Caused by Plasma Cloud Emitted from Solar Flare
• Mixed Duct-Acinar-Islet Cell Tumor of the Pancreas : Report of a Case
• Colon Carcinoma After Thymectomy for Myasthenia Gravis : Report of a Case
• Biconical Antenna and the One covered with a Concentric Spherical Shell of Electromagnetic Medium
• Coupling Measurement of Coaxial Cables II
• Coupling Measurement of Coaxial Cables
• A Review on Prolate Spheroidal Wave Functions
• Theoretical Study on Collision Frequencies and Recombination Coefficients in the Ionosphere, and Comments on Resistivity of Semiconductors and Metals
• Theory of Polarization Angle for an Electromagnetic Wave : Relation between Polarization and Impedance Matching, Application for Small Reflection Materials
• The dissociation rate of S2 produced from COS pyrolysis.
• Relationship between Physical Activity Level and Hip Joint Pain in Adult Women With Chiari Pelvic Osteotomy
• The reaction of hydrogen bromide with nitrogen oxide in shock waves.
• Duodenal Duplication Cyst of the Ampulla of Vater
• The thermal decomposition of CF3I in Ar.
• The thermal unimolecular decomposition of methyl chloride behind shock waves.
• The thermal gas-phase decomposition of vinyl bromide.
• The reaction of hydrogen chloride with nitrogen oxide in shock waves.

もっと見る 閉じる

スポンサーリンク