Diazotization of aromatic primary amines of weak basicity. II. Reduction of arenediazonium salts with alkylbenzene derivatives.
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概要
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The diazonio group of arenediazonium salts derived from weakly basic amines were efficiently substituted by hydrogen with alkylbenzenes in sulfuric acid. Several types of evidence, including kinetic results and experiments to trap an intermediate, indicated that the reduction occurs <I>via</I> an aryl radical intermediate. In the reduction with toluene, analyses of by-products suggested a radical chain mechanism, which would involve a propagation cycle caused by electron transfer from the benzyl radical to the diazonio group.
- 公益社団法人 日本化学会の論文
著者
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Hashida Yoji
Department of Chemistry, Faculty of Engineering, Gunma University
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Matsui Kohji
Department of Chemistry, Faculty of Engineering, Gunma University
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Takagishi Ikuo
Department of Chemistry, Faculty of Engineering, Gunma University
関連論文
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