Synthesis and characterization of metal complexes with schiff bases obtained from N,N'-bis(3-aminopropyl)piperazine and salicylaldehyde derivatives.
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概要
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Cobalt(II), nickel(II), cobalt(III), manganese(III), and iron(III) complexes have been synthesized with Schiff bases (abbreviated as X-sal-prpi) derived from <I>N</I>,<I>N</I>′-bis(3-aminopropyl)piperazine and salicylaldehyde derivatives. On the basis of electronic spectra, infrared spectra, and magnetic data, the structures of the metal complexes are discussed. Complexes of the type Co<SUP>II</SUP>(X-sal-prpi) are five-coordinated, and M<SUP>III</SUP>(X-sal-prpi)ClO<SUB>4</SUB> consist of six-coordinated [M(X-sal-prpi)]<SUP>+</SUP> and free ClO<SUB>4</SUB><SUP>−</SUP> ions, the ligands X-sal-prpi being quinquidentate in the former and sexadentate in the latter.
- 公益社団法人 日本化学会の論文
著者
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Kuma Hiro
Institute Of Chemistry College Of General Education Osaka University
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Yamada Shoichiro
Institute of Chemistry, College of General Education, Osaka University
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