The reaction of 2-(trialkylsiloxy)furans with lead(IV) acetate. The synthesis of dl-pyrenophorin.
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概要
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The reaction of 2-(trimethylsiloxy)furans with lead(IV) acetate afforded the corresponding α,β-unsaturated γ-acetoxy-γ-lactones in good yields. The lactones were easily converted into the corresponding 3-acylacrylic acids. Utilizing this reaction, <I>dl</I>-pyrenophorin was synthesized.
- 公益社団法人 日本化学会の論文
著者
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Asaoka Morio
Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University
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Yanagida Noboru
Department Of Agricultural Chemistry The University Of Tokyo:(present Office)biological Science Inst
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Takei Hisashi
Department Of Life Chemistry Tokyo Institute Of Technology
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Sugimura Naoyuki
Department of Life Chemistry, Tokyo Institute of Technology
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Yanagida Noboru
Department of Life Chemistry, Tokyo Institute of Technology
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