Nucleophilic reactions of hexafluoro-1,2-epoxypropane with 1,2-bifunctional ethanes.
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概要
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Reactions between hexafluoro-1,2-epoxypropane and 1,2-bifunctional ethanes were studied. Ethylenediamine, 2-aminoethanol and 2-aminoethanethiol gave corresponding <I>N</I>- and <I>O</I>-pentafluoropropionylated products, while ethylene glycol, 2-mercaptoethanol, and 1,2-ethanedithiol afforded ring closed products, such as 1,4-dioxanone, 1,4-oxathianone, and 1,4-dithianone compounds.
- 公益社団法人 日本化学会の論文
著者
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Hamouda Hamdy
Department of Chemical Technology, Tokyo Institute of Technology
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Ishikawa Nobuo
Department of Chemical Technology, Tokyo Institute of Technology
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Kawa Hajimu
Department of Chemical Technology, Tokyo Institute of Technology
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