Solubility of some organic mercury(II) halides in water.
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概要
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The solubilities of methylmercury(II) chloride (MMC), methylmercury(II) bromide (MMB), methylmercury(II) iodide (MMI), ethylmercury(II) chloride (EMC), and ethylmercury(II) bromide (EMB) in water have been determined over the temperature range of 10–55 °C (20–40 °C for MMC and EMC). The temperature dependence of the solubilities expressed as mole fractions <I>x</I><SUB>2</SUB> was given by the following equations:<BR>& logx_2(MMC)=-1059/T+0.176 (20–40°C)<BR>& logx_2(MMB)=-1094/T-0.263 (10–55°C)<BR>& logx_2(MMI)=-463/T-3.246 (10–25°C)<BR>& logx_2(MMI)=5.498×10^6(1/T)^2-3.711×10^4(1/T)+57.814 (25–55°C)<BR>& logx_2(EMC)=-1048/T-0.612 (20–40°C)<BR>& logx_2(EMB)=-179/T-4.293 (10–25°C)<BR>& logx_2(EMB)=5.389×10^6(1/T)^2-3.603×10^4(1/T)+55.322 (25–55°C) <BR>The thermodynamic parameters for the transfer process from solid to saturated aqueous solution were also determined.
- 公益社団法人 日本化学会の論文
著者
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Kai Fumiaki
Department Of Chemistry Faculty Of Science Kumanoto University
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TAJIMA KOOJI
Kumamoto Municipal Institute of Public Health
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Kai Fumiaki
Department of Chemistry, Faculty of Science, Kumamoto University
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Kawahara Tetsuo
Department of Chemistry, Faculty of Science, Kumamoto University
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