The crystal structure of di-.MU.-bromo-tris(triphenylphosphine)dicopper(II).
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概要
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The crystal structure of the Cu<SUB>2</SUB>Br<SUB>2</SUB>(PPh<SUB>3</SUB>)<SUB>3</SUB>·1.5C<SUB>6</SUB>H<SUB>6</SUB> complex has been determined by three dimensional X-ray analysis. The crystals are monoclinic, and the space group is P2<SUB>1</SUB>/c, with unit-cell parameters of <I>a</I>=14.122 (3), <I>b</I>=19.573 (4), <I>c</I>=25.985 (7) Å, β=128.99 (1)°, and <I>Z</I>=4. In the Cu<SUB>2</SUB>Br<SUB>2</SUB>(PPh<SUB>3</SUB>)<SUB>3</SUB> molecule, one copper atom is three-coordinate, and the other, four-coordinate.
- 公益社団法人 日本化学会の論文
著者
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Kushi Yoshihiko
Department Of Chemistry Graduate School Of Science Osaka University
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Okuda Tsutomu
Department Of Bio-recycling Faculty Of Engineering Hiroshima Kokusai Gakuin University
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Negita Hisao
Department Of Chemistry Faculty Of Science Hiroshima University
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Kuramoto Masahiro
Department of Chemistry, Faculty of Science, Hiroshima University
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Hiura Morio
Department of Chemistry, Faculty of Science, Hiroshima University
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