SbCl5 complexes of pyridine N-oxide and trimethylamine oxide as the oxidizing agent.
スポンサーリンク
概要
- 論文の詳細を見る
A 1:1 complex of pyridine <I>N</I>-oxide or trimethylamine oxide with SbCl<SUB>5</SUB> acted as an oxidizing agent to benzyl alcohol, bezoin, furoin, and thiophenols more easily than <I>via</I> the oxides to give benzaldehyde, benzil, furil, and the corresponding disulfides respectively. The trimethylamine oxide–SbCl<SUB>5</SUB> also oxidized <I>p</I>-xylene to <I>p</I>-tolualdehyde under nitrogen and to <I>p</I>-toluic acid under air.
- 公益社団法人 日本化学会の論文
著者
-
Matsuura Teruo
Department Of Materials Chemistry Faculty Of Science And Technology Ryukoku University
-
Yamamoto Jiro
Department Of Material Science Faculty Of Engineering Tottori University
-
Otani Norio
Department of Industrial Chemistry, Faculty of Engineering, Tottori University
-
Otani Norio
Department of Emergency and Critical Care Medicine, St. Luke's International Hospital, Japan
-
Umezu Masahiro
Department of Industrial Chemistry, Faculty of Engineering, Tottori University
-
Murakami Mitushige
Department of Industrial Chemistry, Faculty of Engineering, Tottori University
-
Kameoka Noriaki
Department of Industrial Chemistry, Faculty of Engineering, Tottori University
関連論文
- Oxidation of Benzoins with Pyridine N-oxide-SbCl_5 (1 : 1) Complexes^+
- Stereochemistry and Biological Activity of Methyl Hydrogen 3-Phenyl-2,2'-iminodipropionate Produced by Botrytis squamosa
- 4-ニトロピリジンN-オキシド-SbCl5(1:1)錯体とベンゾピナコールとの反応
- ピリジンN-オキシド-SbCl5(1:1)錯体とベンゾピナコ-ルとの反応
- Efficient Synthesis of the Optically Active Cyclopentane Derivative, A Versatile Intermediate Toward the Euphorbia Diterpenes
- SLD2 OXIDATIVE STRAND SCISSION OF DNA
- Effect of the Migrating Group on the Fries Rearrangement of 4-Biphenylyl 4-Substituted Benzoates〔和文〕
- Syntheses and Biological Activities of (2S,2'S)- and (2S,2'R)-Dimethyl 3-Phenyl-2,2'- oxydipropionate, Ether Analogues of a Plant-growth Regulator Isolated from Botrytis squamosa
- 塩化鉄(III)-塩化水素錯体を用いたN-クロロアセトアニリド類のOrton転位
- D-17-2 Model Reactions for the Biosynthesis of Thyroxine(Biosynthesis)
- Clinical Significance of Plasma Ammonia in Patients with Generalized Convulsion
- Photoreaction between Carbazole and trans-Stilbene Occurring at the Interface of Their Crystallites
- Theiler's Murine Encephalomyelitis Virus (TMEV) Subgroup Strain-Specific Infection in Neural and Non-Neural Cell Lines
- PD20 DNA STRAND SCISSION BY NEOCARZINOSTATIN : REACTION OF SELF-COMPLEMENTARY OLIGONUCLOETIDE
- PA159 ISOPRENYLCOUMARIN FROM MERRILLIA CALOXYLON
- Formose reactions. II. The photochemical formose reaction.
- Oxidizing action of complex of N,N-dimethylbenzylamine oxide with SbCl5.
- Synthesis of DMSO-SbCl5(1:1) complex and its oxidizing action toward alcohols.
- Oxidative ring cleavage of 3,5-di-t-butyl-catechol and -o-benzoquinone by base-catalyzed oxygenation.
- Photochemical cis-trans isomerization of 2,4,5-triphenylimidazolines.
- Thermochemical studies on 2,4,6-triisopropylbenzophenone and its photo-isomer, 3',5'-diisopropyl-4,4-dimethyl-3-phenyl-1,2-benzocyclobuten-3-ol. Evaluation of magnitude of light energy stored in the latter molecule.
- Formation of ketone diperoxides from ozonation of O-methyloximes.
- Photoinduced Reactions. LXVIII. Photochemical Dehydrogenation of Imidazolines to Imidazoles
- Base Catalyzed Oxygenation of 3,5-Di-t-butylpyrocatechol and Its Related Compounds
- Base-catalyzed Oxygenation of 2,6-Di-t-butylphenols. A Convenient Method for Preparation of p-Quinols
- Coumarin-4-carboxylic Acids from Coumaran-2,3-diones
- Steric Effects of Alkyl Substituents upon the Opening of the Lactone Ring of Coumaran-2,3-diones
- Mechanism of dye-sensitized photooxidation of tryptophan, tryptamine, and their derivatives. Singlet oxygen process in competition with type I process.
- Photoinduced Reactions. XLIII. Photochemical Reactions of 4-Hydroxy-2,5-cyclohexadienones
- Photoreactions of flavanones.
- SbCl5 complexes of pyridine N-oxide and trimethylamine oxide as the oxidizing agent.