Pseudo-sugars. VII. Synthesis of pseudo-hexopyranose derivatives with .ALPHA.- and .BETA.-gluco configurations.

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概要

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• Several derivatives of pseudo-hexopyranose (5-hydroxymethyl-1,2,3,4-cyclohexanetetrol) with α-gluco, (1,2,4/3,5), and β-gluco, (1,3,5/2,4), configurations were synthesized starting from the compounds obtained by <I>cis</I>-hydroxylation and oxyamination of DL-di-<I>O</I>-acetyl-(1,3/2)-3-bromomethyl-5-cyclohexene-1,2-diol. The <SUP>1</SUP>H NMR chemical shifts of the acetyl methyl protons of the several acetyl derivatives of <I>N</I>-(<I>p</I>-tolylsulfonyl)-pseudoglucosamines are discussed.

• 公益社団法人 日本化学会の論文

著者

• Kondoh Takashi

  Department of Applied Chemistry, Faculty of Engineering, Keio University

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