A simple regioselective partial hydrolysis of Di-O-isopropylidene monosaccharides with copper(II) ion.
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概要
- 論文の詳細を見る
Copper(II) ion was found to be effective for regioselective removal of the 5,6-<I>O</I>-isopropylidene group of α-D-mannose and α-D-glucose derivatives in alcohols at ambient temperature.
- 公益社団法人 日本化学会の論文
著者
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IWATA Masaaki
The Institute of Physical and Chemical Research
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Ohrui Hiroshi
The Institute of Physical and Chemical Research
関連論文
- Crystal Structures of N^2, N^5, N^8-Tri-p-toluenesulfonyl-2,5,8-triaza[9]-paracyclophane and N^2, N^5, N^8-Tri-p-toluenesulfonyl-14-hydroxy-15-hydroxymethyl-O^, O^′-isopropylidene-11-methyl-2,5,8-triaza[9](2,5)pyridinophane
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- Crystal Structure of N^1, N^-Dibenzyl-N^5, N^, N^, N^-tetra(toluene-p-sulfonyl)-1, 5, 10, 14, 18, 23-hexaazacyclohexacosane : New 26-Membered Hexaaza-Coronand
- Preferential introduction of a pyridylmethyl group into sulfonamides as an approach to an intramolular transimination.
- An improved oxidation method of pyridoxine.
- A simple regioselective partial hydrolysis of Di-O-isopropylidene monosaccharides with copper(II) ion.
- Pyridoxal model compounds. II. The Diels-Alder reaction of 9-substituted 2-methoxyanthracenes.
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- Aldol condensation of aldehydes with ketones promoted by the copper(II) ion. Orientation to the chemical model for metalloaldolases.
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