Multiatomic ion model for interdiffusion in the system Na2O-CaO-SiO2.
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概要
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Concentration distributions after interdiffusion at 1200 °C were analysed for the diffusion couple of average composition 16Na<SUB>2</SUB>O·12CaO·72SiO<SUB>2</SUB> (wt%) in terms of self-diffusion coefficients of constituent elements. Theoretical calculation was conducted using a multiatomic ion model assuming that Si migrates with oxygens as a silicate ion. The composition of the silicate ion was estimated by determining the parameters in the diffusion equation so as to provide the best fit of the theoretical calculations to the experimental concentration profiles.
- 公益社団法人 日本化学会の論文
著者
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Oishi Yasumichi
Department Of Nuclear Engineering Faculty Of Engineering Kyushu University
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Nanba Masao
Department of Nuclear Engineering, Kyushu University
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Wakabayashi Hajimu
Government Industrial Research Institute
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