The isomerization of butenes over KC8.
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概要
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The isomerization of butenes over KC<SUB>8</SUB> has been investigated. The double-bond-migration and the cis-trans isomerization took place over KC<SUB>8</SUB>, but the skeletal isomerization could not be observed. From the rates of reactions and the selectivity ratios, all six of the relative rate constants and the activation energies of reaction were determined. The reaction paths on the triangular graph calculated from the rates constants show the <I>cis</I>-convex-type profile, which suggests one of the catalytic characteristics of KC<SUB>8</SUB>.
- 公益社団法人 日本化学会の論文
著者
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Imamura Hayao
Department Of Advanced Materials Science And Engineering Faculty Of Engineering Yamaguchi University
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Tsuchiya Susumu
Department Of Advanced Materials Science And Engineering Faculty Of Engineering Yamaguchi University
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Misumi Takatoshi
Department of Industrial Chemistry, Faculty of Engineering, Yamaguchi University
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Ohuye Noriyuki
Department of Industrial Chemistry, Faculty of Engineering, Yamaguchi University
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