Infrared intensities of bending fundamentals in gaseous HCCCN and DCCCN.
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概要
- 論文の詳細を見る
The infrared spectra of three bending fundamentals (ν<SUB>5</SUB>, ν<SUB>6</SUB>, and ν<SUB>7</SUB>) of gaseous cyanoacetylene and cyanoacetylene-<I>d</I> have been measured and their integrated absorption coefficients <I>A</I>(ν<SUB>i</SUB>) have been determined. The spectral pattern of ν<SUB>5</SUB> fundamental region in HCCCN has been interpreted by assuming the Fermi resonance between <I>v</I><SUB>5</SUB>=1 and <I>v</I><SUB>7</SUB>=3 states. On the basis of the experimental intensity data and the normal coordinate treatment, the dipole-moment derivatives with respect to the internal bending coordinates have been calculated.
- 公益社団法人 日本化学会の論文
著者
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Onaka Takashi
Department Of Astronomy Faculty Of Science University Of Tokyo
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Nakada Yoshikazu
Department Of Astronomy University Of Tokyo
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Onaka Takashi
Department of Astronomy, Faculty of Science, The University of Tokyo
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Deguchi Shuji
Department of Astronomy, Faculty of Science, The University of Tokyo
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Nakada Yoshikazu
Department of Astronomy, Faculty of Science, The University of Tokyo
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Uyemura Masakatsu
Department of Industrial Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics
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