The reaction of bis(dimethylglyoximato)(pyridine)cobalt(I), cobaloxime(I), with 2-(allyloxy)ethyl halides and the photolysis of the resulting organo-cobaloximes.
スポンサーリンク
概要
- 論文の詳細を見る
The reactions of 2-(allyloxy)ethyl halides with cobaloxime(I) gave (tetrahydro-3-furanyl)methylcobaloximes <I>via</I> an electron transfer from cobaloxime(I) to the halides to give radical anions. The rupture of a halide ion to give an organic radical and the ring closure to give a (tetrahydro-3-furanyl)methyl radical are followed by the radical coupling between the organic radical and the cobaloxime(II). The structures of the organo-cobaloximes were determined by the analyses of the photolysis products under aerobic or anaerobic conditions.
- 公益社団法人 日本化学会の論文
著者
-
Tada Masaru
Department Of Chemistry School Of Science And Engineering Waseda University
-
Okabe Masami
Department of Chemistry, School of Science and Engineering, Waseda University
関連論文
- Alkyl Radical Substitution on Disulfide in the Presence of Cobalt(II) Complexes
- Anisotropy in Strength of a TiAl Base Polycrystal with Unidirectionally Oriented Lamellae
- The Effect of Cobalt(II) Complex on the Reactivity of Thioester in Radical Process
- Dual Nature of (Phenylseleno)cobaloxime in the Reaction with 2-Propynyl Derivatives
- The Autoxidation of Phenols Catalyzed by Phthalocyanine-Fe(II) and Salcomine-pyridine
- Photochemistry of host-guest complex. III. Effect of guest cation on the photoreactivity of acetophenone oxime derivatives having crown ether moiety.
- The photochemistry of the host-guest complex. V. The effect of the sodium ion on the photoreaction of benzil derivatives with a crown ether moiety.
- The photochemistry of the host-guest complex. VII. The photoreaction of dicyanopyrazine derivatives having a crown ether moiety.
- Bromination and mercuration of bis-dimethylglyoximato(1-octenyl)pyridinecobalt(III), 1-octenyl cobaloxime.
- The bromination and the mercuration of bis(dimethylglyoximato)(styryl)pyridinecobalts(III), styryl-type cobaloximes.
- The Photo-induced Diels-Alder reaction of 2-cycloocten-1-one and 2-cyclohepten-1-one.
- The bromination and mercuration of bis-dimethylglyoxymato(alkyl)pyridinecobalt(III), alkyl cobaloxime.
- The photoreaction of benzyl 1-cycloalkenyl ketone in acidic or protic media.
- The reaction of bis(dimethylglyoximato)(pyridine)cobalt(I), cobaloxime(I), with 2-(allyloxy)ethyl halides and the photolysis of the resulting organo-cobaloximes.
- The photo-cycloaddition of 3-cyano-2,4-pentanedione with cyclohexene and its quenching by enol ether.
- Reaction of bis(dimethylglyoximato)(pyridine)styrylcobalt(III) derivatives with arenesulfenyl chloride.
- Photolyses of (2-substituted 2-(alkoxycarbonyl)propyl)cobaloximes.