C-Sulfinylation of Grignard reagents and enamines with sulfinic acid.

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概要

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• Direct <I>C</I>-sulfinylation of Grignard reagents with sulfinic acid (<B>4</B>) in the presence of activating reagents, such as phenyl phosphorodichloridate (<B>1</B>), diphenyl phosphorochloridate (<B>2</B>), and 3-phthalimidooxy-l,2-benzisothiazole 1,1-dioxide, were investigated. β-Keto sulfoxides were also formed by the reaction of enamines with <B>4</B> using <B>1</B> and <B>2</B> under similar conditions.

• 公益社団法人 日本化学会の論文

著者

• Furukawa Mitsuru

  Faculty Of Pharmaceutical Sciences Kumamoto University

• Sekioka Minako

  Faculty of Pharmaceutical Sciences, Kumamoto University

• Noguchi Yoshihide

  Faculty of Pharmaceutical Sciences, Kumamoto University

• Kurogi Kenkichi

  Faculty of Pharmaceutical Sciences, Kumamoto University

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• C-Sulfinylation of Grignard reagents and enamines with sulfinic acid.
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